%nprocshared=8
%mem=8GB
#p opt=maxstep=3 freq=noraman wb97xd/genecp
scrf=(solvent=dichloroethane,smd)

Title Card Required

1 1
 O                 -0.46896800    2.64104000   -0.86617100
 C                  0.66465600    2.79788600   -0.20476000
 O                  1.25386100    1.83066100    0.28608600
 C                 -2.03881200   -0.31976200    0.45484300
 C                 -1.07215300   -0.33753200   -0.55984100
 C                 -3.40000000   -0.43400800    0.20364500
 C                 -3.76458000   -0.56043600   -1.12523800
 C                 -2.76353200   -0.54339400   -2.09732600
 H                 -0.66036100    1.69592600   -0.76897100
 H                 -4.80374300   -0.66477200   -1.41133400
 H                 -3.02807600   -0.62003500   -3.14813500
 Rh                 0.83900800   -0.35763900    0.10020100
 C                  1.51760300   -2.37602300    0.37472800
 H                  0.98732300   -3.06194800    1.02196900
 C                  2.68045600   -1.59252400    0.74548300
 H                  3.13089500   -1.55420900    1.72709300
 C                  3.03100600   -0.82544700   -0.35982500
 H                  3.79411200   -0.05893100   -0.39035600
 C                  1.24052800   -2.15508400   -1.00860100
 H                  0.45637500   -2.62779800   -1.58340200
 C                  2.10515100   -1.11244000   -1.44625200
 H                  2.15104100   -0.69055500   -2.44057800
 C                  1.17471900    4.19166400   -0.12054100
 H                  0.38588500    4.91316200   -0.32788800
 H                  1.60863100    4.36007700    0.86514500
 H                  1.97070100    4.30368000   -0.86404600
 O                 -0.31146700   -0.11328900    1.96199500
 O                 -2.32238900   -0.07212400    2.72966000
 N                 -1.55753900   -0.16131100    1.79893400
 N                 -1.45411600   -0.43346800   -1.83171600
 H                 -4.12509400   -0.42509500    1.01047200

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ









