%nprocshared=20
%mem=8GB
#p opt=(maxstep=3) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                  0.31213500    2.36684200   -1.11739800
 C                  1.44228700    2.32504600   -0.59273800
 O                  1.91195900    1.29445600    0.01361500
 C                 -2.04475900    0.36326000    0.40894000
 C                 -1.20235900    0.25086700   -0.69991100
 C                 -3.40208000    0.08365900    0.34539000
 C                 -3.87640200   -0.35631700   -0.87926500
 C                 -2.98018700   -0.48956600   -1.94403900
 H                 -0.32075400    1.04434000   -0.84579500
 H                 -4.92246700   -0.60139100   -1.01407900
 H                 -3.33475000   -0.85190500   -2.90473300
 Rh                 0.80481100   -0.45035000    0.13631000
 C                  0.68045900   -2.50638200    0.86385800
 H                  0.01031900   -2.80558800    1.65780000
 C                  2.01520700   -1.97813400    1.04031800
 H                  2.52517400   -1.84136700    1.98428000
 C                  2.53696700   -1.67776500   -0.24646500
 H                  3.49560000   -1.21940700   -0.44867800
 C                  0.38095600   -2.48912300   -0.51149900
 H                 -0.56049600   -2.77041000   -0.96408800
 C                  1.51522500   -1.93071400   -1.21085800
 H                  1.58686800   -1.76148000   -2.27655000
 C                  2.35772800    3.51511200   -0.67199500
 H                  1.79950900    4.40559100   -0.95825800
 H                  2.85858500    3.66773900    0.28491600
 H                  3.12546900    3.31440700   -1.42532100
 O                 -0.21468900    0.64817700    1.78430600
 O                 -2.13876400    1.26341600    2.52763500
 N                 -1.45326900    0.78882700    1.65564000
 N                 -1.68187600   -0.18753400   -1.87116100
 H                 -4.04290700    0.18838700    1.21354200

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ







