%nprocshared=20
%mem=8000MB
%chk=CGET_0021_TS_CH_H_Cpstar_F.chk
#p opt=(Ts,noeigentest,calcfc) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                  0.17950400    2.95746800   -0.75029900
 C                  1.40278500    2.86590500   -0.45723800
 O                  1.96228200    1.77230800   -0.12951500
 C                 -1.98929000    0.58168700    0.38096500
 C                 -1.11818400    0.70387100   -0.71206600
 C                 -3.31680800    0.14691600    0.32110400
 C                 -1.64359400    0.40856600   -1.97162300
 C                 -3.74721800   -0.15594000   -0.97863600
 C                 -2.95719400   -0.02023800   -2.11188500
 H                 -0.33098100    1.77414200   -0.71119500
 H                 -1.02480300    0.54123000   -2.85353700
 H                 -3.38973900   -0.24713200   -3.07982400
 Rh                 0.89248000   -0.01116800    0.07159700
 C                  0.81774500   -2.02544200    0.83233800
 C                  2.14500400   -1.45862700    1.03985000
 C                  2.69712700   -1.16278200   -0.24273200
 C                  0.56239900   -2.06591000   -0.56302400
 C                  1.69784700   -1.46448600   -1.24012500
 C                  2.24290700    4.11035500   -0.46559200
 H                  1.88338300    4.80197400   -1.22740600
 H                  2.13860100    4.59573700    0.50954400
 H                  3.29322200    3.86682400   -0.62135500
 O                 -0.16289000    0.93260300    1.77649000
 O                 -2.11494000    1.35861600    2.56573600
 C                 -4.26245300   -0.02067300    1.47817500
 H                 -3.77596300   -0.49063400    2.33474000
 H                 -5.11280800   -0.62949000    1.17454300
 H                 -4.63321000    0.95101400    1.81324000
 N                 -1.41244400    0.97912000    1.66456900
 C                 -0.10343400   -2.50239900    1.90579600
 C                  2.79649800   -1.26715800    2.36908200
 C                 -0.64998300   -2.65459900   -1.20458200
 C                  1.87208600   -1.33277200   -2.71696800
 C                  4.02836900   -0.55353400   -0.52243200
 H                 -1.56350900   -2.36949700   -0.67711100
 H                 -0.74954500   -2.34377000   -2.24425800
 H                 -0.57071900   -3.74622300   -1.18151800
 H                 -1.14787700   -2.40007600    1.60274600
 H                  0.08483100   -3.56088800    2.11271000
 H                  0.04305400   -1.94715100    2.83375900
 H                  2.07191300   -0.94135200    3.11801500
 H                  3.23477100   -2.21142500    2.70816800
 H                  3.58800400   -0.51885600    2.32244800
 H                  4.46756000   -0.11935600    0.37514500
 H                  4.70775100   -1.32237200   -0.90415600
 H                  3.94597300    0.23757400   -1.26991900
 H                  0.91548800   -1.17070500   -3.21680900
 H                  2.53153500   -0.49918000   -2.96366100
 H                  2.31537100   -2.24802000   -3.12301200
 F                 -4.99512300   -0.59089200   -1.13854300

-C -H -O -Si -N -F
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ


