%nprocshared=20
%mem=8GB
#p opt freq=noraman wb97xd/genecp
scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                 -0.48531100    2.63125100   -0.90479800
 C                  0.63445300    2.78887700   -0.22715300
 O                  1.21633800    1.81830000    0.27704300
 C                 -2.02043500   -0.32872400    0.45763600
 C                 -1.06775900   -0.34818700   -0.56362200
 C                 -3.39029700   -0.42997800    0.22170900
 C                 -2.97211600   -0.57050000   -2.02104800
 H                 -0.67094200    1.68174000   -0.79605300
 H                 -3.38965300   -0.66500600   -3.02082800
 Rh                 0.85162600   -0.35519000    0.09285200
 C                  1.54180600   -2.36552300    0.34749600
 H                  1.01346700   -3.07159900    0.97589400
 C                  2.67725500   -1.55605900    0.74876900
 H                  3.10705500   -1.51669800    1.73967400
 C                  3.04040900   -0.77456300   -0.34400800
 H                  3.79106400    0.00483300   -0.34830800
 C                  1.28289100   -2.12933700   -1.03350900
 H                  0.51828900   -2.61026200   -1.62681500
 C                  2.14230200   -1.06989100   -1.44781400
 H                  2.19934800   -0.64018900   -2.43823700
 C                  1.13643100    4.18380100   -0.08480600
 H                  0.48713400    4.88878700   -0.60056000
 H                  1.18854700    4.43079900    0.97898000
 H                  2.15181900    4.23942900   -0.48724300
 O                 -0.27469700   -0.13894400    1.93831100
 O                 -2.26545700   -0.10612500    2.74643900
 N                 -1.52403300   -0.16917900    1.79658900
 H                 -4.10281200   -0.41263300    1.04163000
 N                 -3.85979600   -0.55514100   -1.01548400
 C                 -1.59040800   -0.47103800   -1.85318800
 H                 -0.94386100   -0.48453200   -2.72296500

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ







