%nprocshared=8
%mem=2GB
#p opt freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

0 1
 Si                -1.00441300    0.08666800   -0.11599200
 C                 -1.55958800   -0.14190800    1.68375900
 C                 -1.45171500    1.78937100   -0.82377200
 C                 -1.52907100   -1.29700000   -1.31028100
 H                 -1.09972094    0.61156203    2.28849464
 H                 -0.77935515    2.01100601   -1.62608749
 H                 -1.41288528   -0.94749760   -2.31489483
 C                 -1.17316500   -1.52486100    2.22843200
 C                 -2.98692800   -1.73981800   -1.10565800
 C                 -2.89006000    1.89124500   -1.35100900
 H                 -3.10899500   -2.26106500   -0.14963700
 H                 -3.69295400   -0.90328200   -1.11916900
 H                 -3.28935600   -2.43807800   -1.89582500
 H                 -1.38244600   -1.59218100    3.30321700
 H                 -1.74229900   -2.32135300    1.73590200
 H                 -0.10799700   -1.73777900    2.08549900
 H                 -3.62933700    1.75971000   -0.55282600
 H                 -3.06504800    2.87868200   -1.79625800
 H                 -3.09538100    1.14389600   -2.12447100
 C                  0.85399900    0.07310700   -0.05092300
 C                  2.06949600    0.07654600   -0.02098600
 Br                 3.87580000    0.07646400    0.00411900
 H                 -1.31887546    2.52214875   -0.05546839
 H                 -2.62249295   -0.03107795    1.73714225
 H                 -0.88851890   -2.14120503   -1.16225778

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****

-Br -Rh -Ag -I
LANL2DZ







