%nprocshared=20
%mem=8000MB
%chk=CGET_0021_TS_CH_H_Cpstar_CF3.chk
#p opt=(ts,noeigentest,calcfc) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                  0.99475500    2.87058700   -1.07186700
 C                  2.21747200    2.66436900   -0.84408200
 O                  2.67098600    1.55433400   -0.41741500
 C                 -1.30712100    0.91770000    0.53569300
 C                 -0.55277300    0.82507700   -0.64305400
 C                 -2.65723300    0.57670500    0.67428200
 C                 -1.23546400    0.43707800   -1.79202800
 C                 -3.27673700    0.16042400   -0.52275400
 C                 -2.58748800    0.11721300   -1.73134100
 H                  0.35365500    1.77434400   -0.84909500
 H                 -0.71524000    0.40759000   -2.74422400
 H                 -3.11742100   -0.17823400   -2.62898700
 Rh                 1.42725200   -0.05411600    0.04593000
 C                  1.33310700   -1.93458500    1.10610800
 C                  2.71251700   -1.50671000    0.93772500
 C                  2.98533500   -1.46229400   -0.46704900
 C                  0.75729000   -2.11469300   -0.17957300
 C                  1.76628100   -1.76779400   -1.16810700
 C                  3.19842900    3.78100900   -1.05511200
 H                  2.81038100    4.49666900   -1.77892300
 H                  3.33941900    4.29394100   -0.09891400
 H                  4.16239700    3.38463600   -1.37405000
 O                  0.68102700    1.19591400    1.70713600
 O                 -1.09535400    2.06963600    2.54255200
 C                 -3.39940600    0.61689500    1.98631800
 H                 -2.74180400    0.39924000    2.82778400
 H                 -4.21575100   -0.10120200    1.99511900
 H                 -3.81622100    1.61333200    2.15258200
 N                 -0.55364400    1.42746300    1.68116800
 C                  0.64703100   -2.13280600    2.41589100
 C                  3.69022200   -1.23815900    2.03279000
 C                 -0.62403500   -2.61476700   -0.45084700
 C                  1.60856200   -1.84945900   -2.65053300
 C                  4.28855800   -1.06655900   -1.07398900
 H                 -1.36229700   -2.12584500    0.18928100
 H                 -0.91616200   -2.44617800   -1.48663200
 H                 -0.66611400   -3.69079600   -0.25595300
 H                 -0.43755400   -2.06803000    2.31066400
 H                  0.88905400   -3.12479500    2.81103700
 H                  0.97090000   -1.39136000    3.14893300
 H                  3.20287500   -0.78716300    2.89931600
 H                  4.15558700   -2.17578400    2.35445800
 H                  4.47811100   -0.56226600    1.69711400
 H                  4.62275300   -0.10637200   -0.67299700
 H                  5.04380300   -1.82267100   -0.83960800
 H                  4.21676600   -0.97672100   -2.15775100
 H                  0.56639600   -1.72273100   -2.94636400
 H                  2.19979000   -1.08255500   -3.15424000
 H                  1.94554800   -2.82848100   -3.00655200
 C                 -4.73379500   -0.26626800   -0.51836600
 F                 -4.89268400   -1.39652600    0.19452900
 F                 -5.51994900    0.67100800    0.02007900
 F                 -5.17798200   -0.50932700   -1.75484400

-C -H -O -Si -N -F
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ


