%nprocshared=20
%mem=8000MB
%chk=CGET_0004_TS_CH_AMLA.chk
#p opt=(ts,noeigentest,calcfc) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 C                  2.53017300    0.67321600   -1.04357900
 C                  2.21693600    0.01574900    0.16162400
 C                  3.72091400    1.39313100   -1.26875500
 C                  3.18825500    0.01242300    1.16357700
 C                  4.64523000    1.35810600   -0.22742900
 C                  4.39489200    0.66456300    0.95607400
 H                  2.99080500   -0.47682800    2.11090000
 H                  5.58956500    1.87670700   -0.35230200
 H                  5.15332200    0.64428200    1.73159500
 Rh                 0.70145200   -1.35405400    0.00168300
 C                  1.35252600   -3.45107200   -0.35753900
 H                  2.03997400   -3.73448600   -1.14210900
 C                 -0.09492900   -3.39224500   -0.48165000
 H                 -0.65308100   -3.60365100   -1.38360900
 C                 -0.63143700   -3.01915000    0.75861900
 H                 -1.67586600   -2.87120700    0.99058100
 C                  1.68794900   -3.11033000    0.96408000
 H                  2.68639100   -3.03950300    1.37182300
 C                  0.47365500   -2.73917500    1.63946500
 H                  0.39217300   -2.42222600    2.67063600
 O                  0.75189200   -0.46324900   -1.93444400
 O                  1.50789000    1.20401000   -3.05724100
 C                  4.04419700    2.13546200   -2.53572500
 H                  3.98616000    1.48489900   -3.41238000
 H                  5.05293600    2.54566000   -2.47275800
 H                  3.34130500    2.95401300   -2.70425700
 N                  1.56525600    0.49753600   -2.08120000
 Si                -2.45547200    0.37344000   -0.29285800
 C                 -2.82879800    2.22220500   -0.45799600
 C                 -2.61031900   -0.56403700   -1.93361700
 C                 -3.36927100   -0.52314900    1.11839800
 H                 -2.07434600    2.58748000   -1.17017600
 H                 -1.90605300   -1.40486400   -1.84784700
 H                 -3.35399000   -1.58871900    0.84344300
 C                 -2.65187600    2.99322400    0.85824500
 C                 -4.21348500    2.50465500   -1.06849900
 C                 -2.70007000   -0.37165700    2.49286500
 C                 -4.84962900   -0.10937200    1.19744300
 C                 -2.17649900    0.27884900   -3.14384000
 C                 -4.01373000   -1.15255100   -2.15551500
 H                 -3.27234700   -0.90380800    3.26048000
 H                 -1.67783100   -0.76437000    2.50370100
 H                 -2.64425500    0.67887000    2.79632800
 H                 -4.95171800    0.92766700    1.53146600
 H                 -5.36668200   -0.20499000    0.23850500
 H                 -5.38064500   -0.73647100    1.92125300
 H                 -4.33151100    3.57877400   -1.24588000
 H                 -4.36409800    1.99828200   -2.02565600
 H                 -5.02069100    2.19821500   -0.39761600
 H                 -2.78775400    4.06727400    0.69351700
 H                 -3.39354000    2.68605300    1.60315600
 H                 -1.66046100    2.85064500    1.29812800
 H                 -4.77453300   -0.36794900   -2.22713000
 H                 -4.04562900   -1.71417000   -3.09526300
 H                 -4.31472000   -1.83455100   -1.35404500
 H                 -1.17574100    0.70026200   -3.02450700
 H                 -2.16392500   -0.33619700   -4.04988600
 H                 -2.87245700    1.10369500   -3.32425100
 C                 -0.63295800    0.29239100    0.22562300
 C                  0.41628200    0.62483700    0.86530100
 Br                 0.82906900    1.68572100    2.33792200

-C -H -O -Si -N -F
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ




