%nprocshared=8
%mem=8000MB
%chk=CGET_0021_TS_CH_H_Cpstar_OCH3.chk
#p opt=(ts,noeigentest,calcfc) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                  0.49862500    2.86614000   -1.04549200
 C                  1.73269900    2.72100200   -0.84263300
 O                  2.24775500    1.63077500   -0.43493800
 C                 -1.69606000    0.79003400    0.56562700
 C                 -0.94357400    0.74277400   -0.62200000
 C                 -3.02951600    0.42228000    0.70455800
 C                 -1.63069700    0.33900800   -1.76377400
 C                 -3.66494100    0.01110700   -0.49832700
 C                 -2.97479800   -0.01553500   -1.71376300
 H                 -0.08980800    1.74051600   -0.82390800
 H                 -1.11642800    0.33027900   -2.72027400
 H                 -3.48412900   -0.30456300   -2.62492600
 Rh                 1.08601000   -0.04030300    0.03811800
 C                  1.06297900   -1.93115200    1.06867800
 C                  2.42640000   -1.43715700    0.94985000
 C                  2.74230700   -1.36128100   -0.44093000
 C                  0.53892400   -2.12136600   -0.23807400
 C                  1.55845000   -1.70474600   -1.18742900
 C                  2.65437500    3.88676700   -1.06025300
 H                  2.21440300    4.59345500   -1.76283700
 H                  2.79664400    4.39179100   -0.10008900
 H                  3.62774800    3.54239200   -1.41024300
 O                  0.29042800    1.14703000    1.72118300
 O                 -1.52274900    1.86736900    2.61874900
 C                 -3.81907800    0.41672600    1.98447600
 H                 -3.19804800    0.18476700    2.84990800
 H                 -4.62649300   -0.31090500    1.91268600
 H                 -4.26476300    1.39974700    2.16117000
 N                 -0.95710100    1.29901700    1.72081500
 C                  0.34627200   -2.18265900    2.35317200
 C                  3.35278600   -1.12686300    2.07870400
 C                 -0.80652400   -2.68404500   -0.56050500
 C                  1.45641300   -1.76290800   -2.67620900
 C                  4.03935800   -0.88290600   -1.00381200
 H                 -1.58577700   -2.24124300    0.06477200
 H                 -1.07502400   -2.50867400   -1.60172800
 H                 -0.79971600   -3.76437300   -0.38532100
 H                 -0.73646400   -2.15423900    2.21561000
 H                  0.61304700   -3.17210700    2.73843700
 H                  0.61923700   -1.44285900    3.10821100
 H                  2.81780800   -0.68561000    2.92195200
 H                  3.83962700   -2.04355800    2.42764800
 H                  4.12568200   -0.42356600    1.76494000
 H                  4.15091900    0.19242100   -0.83198000
 H                  4.87082300   -1.39953200   -0.51766100
 H                  4.10048600   -1.06863900   -2.07659900
 H                  0.41932500   -1.68292100   -3.00486400
 H                  2.02098000   -0.95204800   -3.14039400
 H                  1.85691000   -2.71357200   -3.04332500
 O                 -4.95359100   -0.32893400   -0.36579900
 C                 -5.68982900   -0.73779800   -1.50925600
 H                 -6.69463600   -0.95241400   -1.15025800
 H                 -5.73299500    0.06118000   -2.25656600
 H                 -5.25953400   -1.64195800   -1.95357300

-C -H -O -Si -N -F
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ


