%nprocshared=12
%mem=2GB
# sp wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 C                 -0.40749600    1.43974900   -0.28103000
 C                  0.57689300    0.69646100   -0.35291800
 C                 -1.37280800   -2.57757300   -1.19607900
 C                 -1.25826000   -1.46580900   -2.06679600
 C                 -2.54745500   -2.40058800   -0.39011500
 H                 -0.45246200   -1.28367900   -2.76427000
 H                 -2.90205200   -3.07352700    0.37817800
 C                 -2.38757700   -0.60529000   -1.83721300
 H                 -2.58919500    0.32478100   -2.35055900
 C                 -3.19063200   -1.19751000   -0.82612900
 H                 -4.08292600   -0.76380900   -0.39409400
 H                 -0.64430700   -3.37029600   -1.08757500
 Si                 2.31251900   -0.04271900   -0.39395000
 C                  2.98925200    0.17738500    1.34958200
 H                  2.56476300   -0.61444700    1.97802900
 C                  2.17676800   -1.83691000   -0.93293300
 H                  1.46484400   -2.33853500   -0.26783900
 C                  3.23856000    1.00634500   -1.64888500
 H                  2.78429300    0.85184300   -2.63566600
 O                 -0.02122300   -1.32604800    1.64759900
 C                 -0.67587900   -0.54514900    2.41130300
 O                 -1.67191000    0.05220600    1.89065200
 C                 -0.26581800   -0.30441600    3.82085100
 H                  0.46461000    0.51138800    3.83053900
 H                 -1.12730300   -0.01030600    4.42202400
 H                  0.20648500   -1.19658900    4.23436400
 Rh                -1.22518700   -0.75354800   -0.01905400
 C                  4.52281000    0.16706900    1.42997800
 C                  3.28400100    2.50157500   -1.31188800
 C                  3.51915600   -2.58224300   -0.91584000
 H                  4.86021500    0.28522900    2.46494300
 H                  4.94748400   -0.76864000    1.05208100
 H                  4.96057200    0.98483400    0.84799500
 H                  3.92159300   -2.65451900    0.09957200
 H                  3.40589100   -3.60280400   -1.29577800
 H                  4.27154100   -2.08483100   -1.53730100
 H                  3.84809300    3.06091000   -2.06521000
 H                  2.27832500    2.93413200   -1.26745100
 H                  3.76138600    2.68156600   -0.34275200
 Br                -1.52721800    2.86071300   -0.19524300
 H                  1.74211800   -1.86598900   -1.93997500
 H                  4.25797200    0.60462900   -1.72100700
 H                  2.60478200    1.12357400    1.75064300

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****
-Ag     
S   1   1.00
      2.9500000              1.0000000
S   1   1.00
      2.1490000              1.0000000
S   1   1.00
      0.6684000              1.0000000
S   1   1.00
      0.0997000              1.0000000
S   1   1.00
      0.0347000              1.0000000
P   1   1.00
      6.5530000              1.0000000
P   1   1.00
      1.5650000              1.0000000
P   1   1.00
      0.5748000              1.0000000
P   1   1.00
      0.0833000              1.0000000
P   1   1.00
      0.0252000              1.0000000
D   2   1.00
      3.3910000              0.1396938
      1.5990000              0.4744421
D   1   1.00
      0.6282000              1.0000000
D   1   1.00
      0.2108000              1.0000000
F   1   1.00
      1.6110000              1.0000000
****

-Br
LANL2DZ
-I
LANL2DZ
-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857
-Ag
AG-ECP     3     28
f potential
  5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
  5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
  5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
  5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121






