%nprocshared=8
%mem=2GB
#p opt freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

0 1
 C                  0.85399900    0.07310700   -0.05092300
 C                  2.06949666    0.07652152   -0.02100983
 Br                 3.97931257    0.07635665    0.00550707
 C                 -0.68501698    0.08433734   -0.10480891
 C                 -1.39523330    1.14124059    0.46529608
 C                 -1.36893659   -0.96201337   -0.72364030
 C                 -2.78907649    1.15137241    0.41712704
 H                 -0.85577598    1.96562994    0.95377309
 C                 -2.76316968   -0.95153916   -0.77277565
 H                 -0.80932654   -1.79500822   -1.17317918
 C                 -3.47329866    0.10484122   -0.20241233
 H                 -3.34896671    1.98408864    0.86701940
 H                 -3.30212708   -1.77647215   -1.26112461
 H                 -4.57229435    0.11307647   -0.24032025

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****

-Br -Rh -Ag -I
LANL2DZ







