%nprocshared=20
%mem=8GB
#p opt=(maxstep=3) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 C                 -2.65799500   -1.05155900   -0.39378900
 C                 -2.24904400   -0.05607900    0.50719800
 C                 -3.89907700   -1.71254600   -0.32089100
 C                 -3.11259300    0.29542200    1.54176600
 C                 -4.73751700   -1.29882100    0.71183200
 C                 -4.35741500   -0.31261200    1.62328900
 H                 -2.81651600    1.04364800    2.26744800
 H                 -5.71627900   -1.75749200    0.80192600
 H                 -5.04902700   -0.01454100    2.40482800
 Rh                -0.75924000    1.19377200   -0.22753400
 C                 -1.45566000    2.95065700   -1.38926400
 H                 -2.12092200    2.85314000   -2.23621200
 C                 -0.00330900    2.89131300   -1.44282900
 H                  0.58353900    2.74739600   -2.33986500
 C                  0.48846900    3.06307700   -0.13978900
 H                  1.52434700    3.06066200    0.16586500
 C                 -1.83836900    3.15948900   -0.05293700
 H                 -2.85100900    3.21624000    0.32258100
 C                 -0.64598500    3.13608200    0.74588300
 H                 -0.59878400    3.25355700    1.82062100
 O                 -0.93640500   -0.36251000   -1.74005800
 O                 -1.74916900   -2.31632900   -2.11296900
 C                 -4.36479100   -2.75805100   -1.29346600
 H                 -4.24529000   -2.42954700   -2.32969300
 H                 -5.42065800   -2.97329400   -1.11653400
 H                 -3.79654500   -3.68489500   -1.18040400
 N                 -1.75134200   -1.28746200   -1.47376500
 Si                 2.43407900   -0.45141800   -0.04881500
 C                  2.88128200   -2.23611000    0.40984800
 C                  2.51080700   -0.13547000   -1.91517000
 C                  3.35949800    0.89921400    0.91875100
 H                  2.10417800   -2.84268900   -0.07959900
 H                  1.80443900    0.69224600   -2.07368000
 H                  3.29367000    1.79449600    0.28294000
 C                  2.81156800   -2.50905000    1.91846100
 C                  4.24056400   -2.68363100   -0.15154500
 C                  2.72499400    1.23326300    2.27665700
 C                  4.85293100    0.57581500    1.08665300
 C                  2.02200300   -1.33198900   -2.74435800
 C                  3.89134100    0.33773500   -2.39258900
 H                  3.28433000    2.03404700    2.77471500
 H                  1.68720100    1.56523200    2.17630300
 H                  2.73154100    0.36611300    2.94731400
 H                  5.00097800   -0.28301000    1.74988300
 H                  5.34396300    0.35160300    0.13403700
 H                  5.37764800    1.42761000    1.53405400
 H                  4.38791600   -3.75563800    0.02621000
 H                  4.32966300   -2.51498400   -1.22852400
 H                  5.06782700   -2.15811000    0.33595200
 H                  3.00081500   -3.56974000    2.12385500
 H                  3.56754400   -1.93325000    2.46355800
 H                  1.83527600   -2.26268800    2.34409300
 H                  4.65985300   -0.42796500   -2.23697900
 H                  3.86744700    0.55939900   -3.46689300
 H                  4.21629300    1.24746700   -1.87615100
 H                  1.04271500   -1.69385800   -2.41790400
 H                  1.92917900   -1.05435700   -3.80135500
 H                  2.72692100   -2.16760400   -2.69192400
 C                  0.63719600   -0.25126800    0.45717400
 C                 -0.34434800   -0.45132300    1.23453900
 Cl                -0.67175800   -1.06673300    2.78147000

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ







