%nprocshared=20
%mem=8GB
#p opt=maxstep=3 freq=noraman wb97xd/genecp
scrf=(solvent=dichloroethane,smd)

Title Card Required

1 1
 C                  2.15874900   -1.11859700    0.41876400
 C                  1.16340800   -1.11640200   -0.58310200
 C                  3.52741200   -1.23596500    0.17594000
 C                  1.60781600   -1.18518000   -1.91399100
 C                  3.90028900   -1.31662500   -1.16875400
 C                  2.96282100   -1.27862900   -2.19677000
 H                  0.86968100   -1.18708300   -2.70943500
 H                  4.95646600   -1.39630800   -1.40637100
 H                  3.29277700   -1.32942100   -3.22850400
 Rh                 0.72093800    1.22706500   -0.07174100
 C                  2.07980600    3.07081800   -0.01152800
 H                  2.97061600    3.15515100    0.59488100
 C                  0.72022500    3.30480400    0.43717500
 H                  0.43523200    3.65086000    1.42258800
 C                 -0.16926700    3.09680500   -0.66098700
 H                 -1.23585900    3.26273500   -0.65559500
 C                  2.01005700    2.61114400   -1.32155400
 H                  2.83895800    2.25581100   -1.91967500
 C                  0.60882800    2.55815100   -1.72459400
 H                  0.24807000    2.27024900   -2.70248900
 O                  1.10133000    0.20230300    1.96599100
 O                  1.95866800   -1.64903000    2.67364300
 C                  4.55044200   -1.25281700    1.27782000
 H                  4.40376000   -0.43151300    1.98582000
 H                  5.55287900   -1.16260200    0.85700700
 H                  4.49631600   -2.18934500    1.83908800
 N                  1.71365600   -0.86765200    1.78978000
 Si                -2.70241900    0.52602100    0.38637800
 C                 -3.83066400   -0.93284000    0.80483800
 C                 -2.58128700    1.65261800    1.89191400
 C                 -3.38271500    1.45582500   -1.11395700
 H                 -3.27614000   -1.66842100    1.39878500
 H                 -1.87293100    2.46319200    1.67525500
 H                 -3.16414300    2.52657900   -1.02170800
 C                 -4.52273200   -1.61223700   -0.38306100
 C                 -2.89564400    0.92701300   -2.46857000
 C                 -2.16895600    0.92156900    3.17546300
 H                 -3.36520200    1.46170200   -3.30106400
 H                 -1.81137900    1.03811200   -2.57273000
 H                 -3.12234500   -0.13766700   -2.59027800
 H                 -5.17214600   -2.42929400   -0.04999200
 H                 -5.14763500   -0.90468100   -0.93813100
 H                 -3.79911300   -2.03524800   -1.08597600
 H                 -1.18390600    0.45467000    3.06905000
 H                 -2.11715600    1.60565800    4.02924000
 H                 -2.88205500    0.13089300    3.43195600
 C                 -0.93139700   -0.00438000   -0.02131300
 C                 -0.30358000   -1.14011200   -0.29510200
 Br                -1.06818000   -2.90728800   -0.46597000
 H                 -4.59742500   -0.52801500    1.48069800
 H                 -3.55983900    2.13203100    2.02897400
 H                 -4.47674800    1.38241600   -1.06074200

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****

-Br -Rh -Ag -I
LANL2DZ







