%nprocshared=12
%mem=2GB
# sp wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                 -0.18659600   -0.07255600    1.91314300
 C                 -0.49611200    1.16156100    1.91673700
 O                 -1.27897100    1.55495300    0.99059500
 Rh                -1.28423600   -0.38529600    0.11271300
 C                 -2.39312900   -1.13852500   -1.58621100
 H                 -2.22042000   -0.80477500   -2.60066900
 C                 -3.29003800   -0.55288400   -0.66127600
 H                 -3.89137500    0.32950600   -0.83675700
 C                 -3.15854100   -1.24654900    0.59103400
 H                 -3.69619300   -1.02700700    1.50349900
 C                 -1.72714100   -2.23789400   -0.92928300
 H                 -0.97810100   -2.88347000   -1.36829900
 C                 -2.21936800   -2.31668000    0.39619300
 H                 -1.87508000   -3.00174200    1.15977800
 C                  0.02638100    2.10741500    2.94027400
 H                  0.93911400    1.71662800    3.39070500
 H                  0.20424900    3.08274800    2.48369900
 H                 -0.73074300    2.22975800    3.72167000
 O                 -0.62301500    2.51443100   -1.97148400
 O                  0.47396100    4.02303300   -0.85358200
 N                  0.27626600    2.87833100   -1.22157200
 C                  1.15870700    1.86070800   -0.74031500
 C                  2.23787300    2.00872500    0.06260600
 C                  2.83949900    0.74866000    0.38863800
 C                  2.18088600   -0.29675700   -0.17022500
 S                  0.82948900    0.20432300   -1.16899300
 H                  2.59632600    2.96621100    0.41893200
 H                  3.71579600    0.64852500    1.01608300
 Br                 2.58526300   -2.11660300   -0.01669200

-C -H -O -Si -N -F -Cl -S
6-311++G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****
-Ag     
S   1   1.00
      2.9500000              1.0000000
S   1   1.00
      2.1490000              1.0000000
S   1   1.00
      0.6684000              1.0000000
S   1   1.00
      0.0997000              1.0000000
S   1   1.00
      0.0347000              1.0000000
P   1   1.00
      6.5530000              1.0000000
P   1   1.00
      1.5650000              1.0000000
P   1   1.00
      0.5748000              1.0000000
P   1   1.00
      0.0833000              1.0000000
P   1   1.00
      0.0252000              1.0000000
D   2   1.00
      3.3910000              0.1396938
      1.5990000              0.4744421
D   1   1.00
      0.6282000              1.0000000
D   1   1.00
      0.2108000              1.0000000
F   1   1.00
      1.6110000              1.0000000
****

-Br
LANL2DZ
-I
LANL2DZ
-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857
-Ag
AG-ECP     3     28
f potential
  5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
  5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
  5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
  5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121






