%nprocshared=8
%mem=2GB
# sp wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                 -1.49402900    1.88913600    0.51913600
 C                 -1.06792200    2.24143100   -0.62835200
 O                 -0.85262400    1.32244300   -1.47695300
 C                  2.96870200   -0.22321900    0.14251600
 C                  1.64268100   -0.38544900   -0.22123100
 C                  3.31898400    0.36802100    1.34721500
 C                  2.28781700    0.78537200    2.17655700
 C                  0.97551000    0.60327500    1.76720800
 H                  1.36366300   -0.84347700   -1.16136400
 H                  2.49217000    1.25393300    3.13103700
 H                  0.14296800    0.92640900    2.38014100
 Rh                -1.35437300   -0.18067700   -0.00762700
 C                 -1.52891900   -2.30739900    0.38355300
 H                 -0.66949200   -2.90598900    0.65526200
 C                 -1.96028800   -2.03053900   -0.93931400
 H                 -1.51001700   -2.40868400   -1.84690000
 C                 -3.09621700   -1.14538200   -0.86096200
 H                 -3.63760800   -0.73179800   -1.70056800
 C                 -2.35069400   -1.56610000    1.28718700
 H                 -2.26360500   -1.54937000    2.36446300
 C                 -3.34048000   -0.87636100    0.50520200
 H                 -4.08772400   -0.19626500    0.89212800
 C                 -0.78718500    3.67291100   -0.94048000
 H                 -1.40581600    4.32499400   -0.32271900
 H                  0.26605400    3.87504300   -0.71918300
 H                 -0.96033600    3.86977500   -1.99952800
 O                  3.64852500   -1.25683000   -1.79579500
 O                  5.16846200   -0.47769700   -0.46767300
 N                  4.00806500   -0.68780200   -0.77729600
 N                  0.66655900    0.02861900    0.59238000
 H                  4.35953500    0.49439200    1.62055900

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****
-Ag     
S   1   1.00
      2.9500000              1.0000000
S   1   1.00
      2.1490000              1.0000000
S   1   1.00
      0.6684000              1.0000000
S   1   1.00
      0.0997000              1.0000000
S   1   1.00
      0.0347000              1.0000000
P   1   1.00
      6.5530000              1.0000000
P   1   1.00
      1.5650000              1.0000000
P   1   1.00
      0.5748000              1.0000000
P   1   1.00
      0.0833000              1.0000000
P   1   1.00
      0.0252000              1.0000000
D   2   1.00
      3.3910000              0.1396938
      1.5990000              0.4744421
D   1   1.00
      0.6282000              1.0000000
D   1   1.00
      0.2108000              1.0000000
F   1   1.00
      1.6110000              1.0000000
****

-Br
LANL2DZ
-I
LANL2DZ
-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857
-Ag
AG-ECP     3     28
f potential
  5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
  5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
  5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
  5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121






