%nprocshared=8
%mem=8000MB
%chk=CGET_0004_TS_CH_AMLA.chk
#p opt=(ts,noeigentest,calcfc) freq=noraman wB97XD/genecp scrf=(smd,solvent=dichloroethane) 

Opt freq

1 1
 O                 -0.49335100    2.48105000    1.03424200
 C                 -1.65059900    2.38128200    0.54162300
 O                 -2.11976200    1.31106400    0.01909400
 C                  1.87695300    0.33800700   -0.14116100
 C                  0.88387100    0.24654400    0.86385600
 C                  3.22326700   -0.01962500    0.03361400
 C                  1.27568200   -0.24212300    2.11551200
 C                  3.54440000   -0.52349200    1.30791000
 C                  2.60106000   -0.63207400    2.32922000
 H                  0.09703200    1.23762300    0.92980700
 H                  0.54961700   -0.29124400    2.92059000
 H                  4.56868000   -0.83236000    1.49224500
 H                  2.90507700   -1.01704400    3.29772100
 Rh                -0.97705800   -0.43233700   -0.16449900
 C                 -0.74293600   -2.54484000   -0.88182400
 H                  0.06410400   -2.85557000   -1.53225900
 C                 -2.02890500   -2.03369000   -1.31024500
 H                 -2.34922300   -1.90163900   -2.33544500
 C                 -2.78705400   -1.72841300   -0.15098500
 H                 -3.77626300   -1.28943400   -0.13755700
 C                 -0.71834800   -2.53558000    0.53299900
 H                  0.11738500   -2.82334200    1.15667300
 C                 -1.96729600   -1.98151300    1.00124900
 H                 -2.25780100   -1.84620600    2.03432700
 C                 -2.54754200    3.59333500    0.52525700
 H                 -2.29767900    4.18590600   -0.36231100
 H                 -3.59670700    3.30091200    0.46710300
 H                 -2.36389600    4.20676500    1.40923800
 O                  0.15060500    0.70700400   -1.65515200
 O                  2.13306600    1.35872200   -2.22395800
 C                  4.28606100    0.07774300   -1.02519300
 H                  3.95420400   -0.34895400   -1.97619500
 H                  5.18602300   -0.44701100   -0.69811900
 H                  4.54239100    1.12352200   -1.22108700
 N                  1.39549900    0.83102300   -1.41243800

-C -H -O -Si -N -F
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ




