%nprocshared=20
%mem=2GB
# sp wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                 -1.96343600   -1.53326300   -1.12661400
 C                 -2.93881200   -2.00854000   -0.45369800
 O                 -3.56203000   -1.19671000    0.29929600
 C                  1.16172000   -0.42414800    0.96794700
 C                  1.08609800   -1.03353700   -0.25927200
 C                  3.27195200   -0.30293700   -0.20894200
 C                  2.31715900   -0.95886400   -0.94560300
 H                  0.19198900   -1.51248600   -0.64364500
 H                  2.48882000   -1.37324400   -1.93031200
 Rh                -2.15581200    0.34540800   -0.13650100
 C                 -2.02859700    2.38413300    0.56015100
 H                 -1.87210000    2.63411800    1.60110000
 C                 -3.28048600    2.17753200   -0.06336400
 H                 -4.24611800    2.22545700    0.42193900
 C                 -3.03971100    1.75731000   -1.41836500
 H                 -3.79211800    1.49988600   -2.15089300
 C                 -0.99501600    2.14197200   -0.41517100
 H                  0.07093400    2.18842700   -0.23719900
 C                 -1.61750200    1.78427800   -1.63395400
 H                 -1.11085000    1.48702200   -2.54268600
 C                 -3.29411700   -3.45276900   -0.51436900
 H                 -2.99992500   -3.87777600   -1.47478300
 H                 -2.74918700   -3.97292900    0.28056500
 H                 -4.36302900   -3.58772900   -0.34359600
 O                 -1.03462900   -0.65508600    1.59209200
 O                  0.39272900    0.08867200    3.03343800
 N                  0.12497500   -0.31330800    1.91839900
 S                  2.72249300    0.22953400    1.33554500
 Br                 5.04117800    0.03574300   -0.73466600

-C -H -O -Si -N -F -Cl -S
6-311++G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****
-Ag     
S   1   1.00
      2.9500000              1.0000000
S   1   1.00
      2.1490000              1.0000000
S   1   1.00
      0.6684000              1.0000000
S   1   1.00
      0.0997000              1.0000000
S   1   1.00
      0.0347000              1.0000000
P   1   1.00
      6.5530000              1.0000000
P   1   1.00
      1.5650000              1.0000000
P   1   1.00
      0.5748000              1.0000000
P   1   1.00
      0.0833000              1.0000000
P   1   1.00
      0.0252000              1.0000000
D   2   1.00
      3.3910000              0.1396938
      1.5990000              0.4744421
D   1   1.00
      0.6282000              1.0000000
D   1   1.00
      0.2108000              1.0000000
F   1   1.00
      1.6110000              1.0000000
****

-Br
LANL2DZ
-I
LANL2DZ
-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857
-Ag
AG-ECP     3     28
f potential
  5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
  5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
  5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
  5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121






