%nprocshared=20
%mem=8GB
#p opt=maxstep=3 freq=noraman wb97xd/genecp
scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 C                 -2.62202800   -1.12260300   -0.35605500
 C                 -1.69742900   -1.14132400    0.71197900
 C                 -4.00339900   -1.01952800   -0.20619400
 C                 -2.22547600   -0.99823400    2.00425600
 C                 -4.46594000   -0.90533300    1.10902700
 C                 -3.59700400   -0.87924000    2.19455400
 H                 -1.54517500   -1.00916300    2.84918300
 H                 -5.53416500   -0.80827600    1.27312100
 H                 -3.99351100   -0.76777500    3.19753600
 Rh                -0.92127400    1.03390800    0.01634400
 C                 -2.06325600    2.97661300   -0.36609000
 H                 -2.86845900    3.07084100   -1.08132800
 C                 -0.64712400    3.03360700   -0.68601900
 H                 -0.23028600    3.24575800   -1.66212600
 C                  0.09778900    2.86911000    0.51813100
 H                  1.16794200    2.94829500    0.61707400
 C                 -2.17455100    2.65452200    0.98089200
 H                 -3.09148400    2.44234400    1.51525900
 C                 -0.83255400    2.51551500    1.53555000
 H                 -0.60195200    2.30195900    2.57046200
 O                 -1.29944400   -0.13428500   -1.94272800
 O                 -2.34265300   -1.93624700   -2.51681800
 C                 -4.94785500   -0.98942300   -1.37586400
 H                 -4.64497900   -0.24873700   -2.12268100
 H                 -5.95245200   -0.73549500   -1.03462200
 H                 -4.99001700   -1.96419400   -1.86901800
 N                 -2.06190300   -1.08930800   -1.70660000
 Si                 2.42272300   -0.12697000   -0.10491300
 C                  3.34140000   -1.79706800   -0.23802900
 C                  2.41338000    0.83918900   -1.74728300
 C                  3.08308800    0.95923300    1.31984100
 H                  2.65918000   -2.45864800   -0.79044200
 H                  1.59796200    1.56409600   -1.60674800
 H                  2.76561400    1.98020500    1.07618200
 C                  3.64545300   -2.46539500    1.11269300
 C                  4.64254200   -1.69398400   -1.05485300
 C                  2.46381000    0.60241600    2.67879800
 C                  4.61812600    1.00734500    1.40948200
 C                  2.01818100   -0.05673200   -2.92995400
 C                  3.67680500    1.65270100   -2.05628700
 H                  2.82569400    1.28200300    3.46023700
 H                  1.37037400    0.67103000    2.65840400
 H                  2.72169300   -0.41649600    2.98606800
 H                  5.04372300    0.04995200    1.72205600
 H                  5.08360300    1.27919000    0.45750300
 H                  4.92992600    1.75334500    2.15048900
 H                  5.11906800   -2.67946200   -1.13024800
 H                  4.47321500   -1.33705900   -2.07374000
 H                  5.36620200   -1.02159900   -0.58130400
 H                  4.02843800   -3.48118700    0.95387100
 H                  4.41478600   -1.91791600    1.66424500
 H                  2.76855800   -2.54315000    1.75840100
 H                  4.56539000    1.02053800   -2.15474900
 H                  3.55834800    2.19312400   -3.00396500
 H                  3.88223800    2.39811600   -1.28066200
 H                  1.09555100   -0.61206800   -2.73224500
 H                  1.85241700    0.54270800   -3.83386000
 H                  2.80032900   -0.78531300   -3.16591600
 C                  0.56638400   -0.39210500    0.20153100
 C                 -0.23097400   -1.40194600    0.52095800
 Cl                 0.24207800   -3.05881400    0.93429700

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ







