%nprocshared=20
%mem=8000MB
%chk=CGET_0004_TS_CH_AMLA.chk
#p opt freq=noraman wb97xd/genecp scrf=(solvent=dichloroethane,smd)

Title Card Required

1 1
 O                 -1.69864000    1.19110000    1.13596700
 C                 -2.58924100    1.53704600    0.29360200
 O                 -2.77047300    0.76871700   -0.70304700
 C                  1.98050500    0.83488100   -0.13585000
 C                  1.46851400    1.26766500    1.08575900
 C                  3.15771500    0.08837200   -0.27402600
 C                  2.16735400    0.95922400    2.24189100
 C                  3.81308700   -0.22619100    0.91980400
 C                  3.33753100    0.20636100    2.15402400
 H                  0.54715500    1.83737900    1.12119100
 H                  1.79822500    1.30196700    3.20183300
 H                  4.71985100   -0.82067500    0.87070000
 H                  3.88421600   -0.04919500    3.05595500
 Rh                -1.13211700   -0.46949200   -0.10238900
 C                  0.21617300   -2.13683000   -0.43256900
 H                  1.16390000   -2.01503200   -0.94147700
 C                 -1.03812800   -2.39672600   -1.05910800
 H                 -1.20676400   -2.54803100   -2.11615100
 C                 -2.03857600   -2.39834600   -0.03314700
 H                 -3.10232500   -2.52531700   -0.18469200
 C                  0.00435600   -1.94965700    0.96072000
 H                  0.75947900   -1.69325500    1.69089900
 C                 -1.39989900   -2.11940200    1.21106500
 H                 -1.89563200   -2.00738000    2.16598600
 C                 -3.36084800    2.80268900    0.44493200
 H                 -3.23756100    3.21229800    1.44755200
 H                 -2.99224100    3.52560700   -0.28940900
 H                 -4.41674600    2.61861900    0.23560700
 O                 -0.02720300    1.06249800   -1.30401900
 O                  1.79065500    1.61714500   -2.29439400
 C                  3.69767700   -0.39767700   -1.59086600
 H                  2.91053800   -0.74475500   -2.26602200
 H                  4.39332400   -1.22160400   -1.42122200
 H                  4.23642800    0.40282200   -2.10586600
 N                  1.21876500    1.18708300   -1.32154400

-C -H -O -Si -N -F
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ




