%nprocshared=20
%mem=8GB
#p opt freq=noraman wb97xd/genecp
scrf=(solvent=dichloroethane,smd)

Title Card Required

1 1
 C                 -2.06445900    0.78076800    0.51884200
 C                 -1.20255600    1.18998900   -0.51813000
 C                 -3.45062100    0.62606700    0.38340800
 C                 -1.79173000    1.44931200   -1.76308400
 C                 -3.97206800    0.88547100   -0.88068700
 C                 -3.15789700    1.29536100   -1.93698100
 H                 -1.16115400    1.77902800   -2.58194100
 H                 -5.03894800    0.76450700   -1.03737200
 H                 -3.60147800    1.49474200   -2.90634600
 Rh                -0.37123500   -1.30461400   -0.10184000
 C                 -0.84191300   -3.55506500    0.06848600
 H                 -1.35085300   -4.00933700    0.90765600
 C                  0.57299900   -3.18934300    0.04282000
 H                  1.29516200   -3.41539600    0.81582000
 C                  0.86451700   -2.63079900   -1.23947800
 H                  1.83133700   -2.29969300   -1.59212700
 C                 -1.42016900   -3.10452700   -1.10512300
 H                 -2.47013800   -3.13948500   -1.36181500
 C                 -0.38179300   -2.45403400   -1.89719100
 H                 -0.52635600   -1.99533200   -2.86666600
 O                 -0.75812400   -0.48645000    1.95017200
 O                 -1.74355900    1.24679700    2.76929200
 C                 -4.32300800    0.20078000    1.53125600
 H                 -3.91372100   -0.67366900    2.04711700
 H                 -5.31878300   -0.05557600    1.16687200
 H                 -4.42341000    1.00633300    2.26439700
 N                 -1.48700700    0.51996600    1.84570500
 C                  0.97192600    0.21635500   -0.08954800
 C                  0.26698800    1.32406700   -0.30118400
 Br                 0.96895300    3.11605100   -0.33159500
 C                  2.41056800    0.03046600    0.12446300
 C                  2.86307600   -0.64847100    1.26381700
 C                  3.34242600    0.48868100   -0.81484600
 C                  4.22390700   -0.84443500    1.46961900
 H                  2.14243800   -1.01194400    1.99061700
 C                  4.70316300    0.27944900   -0.61060800
 H                  2.99814400    1.00352400   -1.70637000
 C                  5.14677000   -0.38315700    0.53183100
 H                  4.56516700   -1.36028700    2.36169600
 H                  5.41791200    0.63693400   -1.34522600
 H                  6.20866700   -0.54265800    0.69057700

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****
-I
LANL2DZ
D 1 1.0
0.289 1.0
****

-Br -Rh -Ag -I
LANL2DZ







