%nprocshared=20
%mem=8GB
#p opt=(ts,noeigentest,calcfc) freq=noraman wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 C                  2.12557600   -0.35620400    1.00442700
 C                  1.57342900   -0.10473900   -0.26658800
 C                  3.46013600   -0.74544000    1.21616900
 C                  2.40870200   -0.21853300   -1.37886000
 C                  4.25352900   -0.81649000    0.07093300
 C                  3.74501100   -0.54383100   -1.19864400
 H                  2.00923000   -0.05531400   -2.37395200
 H                  5.29893400   -1.08497300    0.18152200
 H                  4.40425400   -0.59660700   -2.05882000
 Rh                -0.01369700    1.25534500   -0.20437000
 C                  0.54491700    3.42050300   -0.21383900
 H                  1.24558100    3.84365100    0.49308600
 C                 -0.88472300    3.26117100    0.00895100
 H                 -1.41578500    3.56724900    0.90040200
 C                 -1.45066700    2.67576300   -1.13975500
 H                 -2.48961500    2.41522300   -1.28520000
 C                  0.84653300    2.90361100   -1.47927600
 H                  1.82861200    2.82777100   -1.92454200
 C                 -0.36916600    2.35663000   -2.02912700
 H                 -0.46598600    1.87325500   -2.99202600
 O                  0.29779600    0.70418000    1.88954100
 O                  1.39037200   -0.61445600    3.18839900
 C                  4.05969500   -1.03228000    2.56334100
 H                  3.88481800   -0.21506700    3.26857500
 H                  5.13601000   -1.17833200    2.45775500
 H                  3.62651000   -1.93487300    3.00156800
 N                  1.24591100   -0.09883800    2.10344600
 C                 -1.22465900   -0.45675200   -0.01308900
 C                 -0.17403400   -0.97240300   -0.54028300
 Br                 0.16855100   -2.48984400   -1.58729300
 C                 -2.60422800   -0.64671000    0.37030400
 C                 -3.34796600    0.39788200    0.93355100
 C                 -3.20883200   -1.89810100    0.16715500
 C                 -4.68047600    0.19897600    1.27396300
 H                 -2.87368000    1.35865900    1.10312100
 C                 -4.54102000   -2.08857600    0.50984600
 H                 -2.63791500   -2.71391700   -0.26373300
 C                 -5.27890100   -1.04137200    1.06061600
 H                 -5.25184000    1.01234500    1.70904400
 H                 -5.00518400   -3.05544100    0.34502600
 H                 -6.32072500   -1.19417300    1.32369100

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ







