%nprocshared=12
%mem=2GB
# sp wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 C                 -2.64799500   -1.06055900   -0.38678900
 C                 -2.21604400   -0.09007900    0.53619800
 C                 -3.89507700   -1.70954600   -0.32189100
 C                 -3.09759300    0.28142200    1.55276600
 C                 -4.73451700   -1.29182100    0.70983200
 C                 -4.35241500   -0.30561200    1.61928900
 H                 -2.79651600    1.01964800    2.28744800
 H                 -5.71627900   -1.74549200    0.79592600
 H                 -5.04702700    0.00245900    2.39382800
 Rh                -0.75524000    1.19977200   -0.23153400
 C                 -1.45866000    2.95565700   -1.39026400
 H                 -2.12292200    2.85714000   -2.23821200
 C                 -0.00530900    2.88831300   -1.44382900
 H                  0.58153900    2.74439600   -2.34086500
 C                  0.48746900    3.06307700   -0.13978900
 H                  1.52334700    3.06066200    0.16586500
 C                 -1.84036900    3.16348900   -0.05593700
 H                 -2.85200900    3.22124000    0.32058100
 C                 -0.64598500    3.13808200    0.74388300
 H                 -0.59978400    3.25255700    1.81862100
 O                 -0.93940500   -0.36451000   -1.74305800
 O                 -1.74816900   -2.32032900   -2.11396900
 C                 -4.36479100   -2.75305100   -1.29546600
 H                 -4.24429000   -2.42554700   -2.33169300
 H                 -5.42065800   -2.96529400   -1.11853400
 H                 -3.79854500   -3.68089500   -1.18140400
 N                 -1.74834200   -1.29246200   -1.47376500
 Si                 2.42507900   -0.45141800   -0.04381500
 C                  2.87828200   -2.23611000    0.41084800
 C                  2.50680700   -0.13547000   -1.91217000
 C                  3.35649800    0.89921400    0.91975100
 H                  2.10217800   -2.84368900   -0.07759900
 H                  1.80143900    0.69224600   -2.07368000
 H                  3.28967000    1.79349600    0.28294000
 C                  2.81156800   -2.51005000    1.91946100
 C                  4.23856400   -2.68163100   -0.15154500
 C                  2.72399400    1.23326300    2.27765700
 C                  4.84993100    0.57481500    1.08565300
 C                  2.02100300   -1.33198900   -2.74335800
 C                  3.88834100    0.33773500   -2.38858900
 H                  3.28233000    2.03604700    2.77471500
 H                  1.68520100    1.56423200    2.17830300
 H                  2.73154100    0.36711300    2.94931400
 H                  4.99897800   -0.28301000    1.74988300
 H                  5.33996300    0.35060300    0.13303700
 H                  5.37464800    1.42761000    1.53305400
 H                  4.38691600   -3.75363800    0.02621000
 H                  4.32766300   -2.51298400   -1.22852400
 H                  5.06582700   -2.15611000    0.33595200
 H                  3.00081500   -3.57074000    2.12485500
 H                  3.56754400   -1.93325000    2.46355800
 H                  1.83527600   -2.26368800    2.34609300
 H                  4.65685300   -0.42796500   -2.23297900
 H                  3.86544700    0.55839900   -3.46289300
 H                  4.21329300    1.24746700   -1.87315100
 H                  1.04171500   -1.69485800   -2.41890400
 H                  1.93017900   -1.05335700   -3.80035500
 H                  2.72692100   -2.16760400   -2.68992400
 C                  0.61619600   -0.24726800    0.45417400
 C                 -0.39034800   -0.45832300    1.21253900
 Cl                -0.66675800   -1.07073300    2.78347000

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****
-Ag     
S   1   1.00
      2.9500000              1.0000000
S   1   1.00
      2.1490000              1.0000000
S   1   1.00
      0.6684000              1.0000000
S   1   1.00
      0.0997000              1.0000000
S   1   1.00
      0.0347000              1.0000000
P   1   1.00
      6.5530000              1.0000000
P   1   1.00
      1.5650000              1.0000000
P   1   1.00
      0.5748000              1.0000000
P   1   1.00
      0.0833000              1.0000000
P   1   1.00
      0.0252000              1.0000000
D   2   1.00
      3.3910000              0.1396938
      1.5990000              0.4744421
D   1   1.00
      0.6282000              1.0000000
D   1   1.00
      0.2108000              1.0000000
F   1   1.00
      1.6110000              1.0000000
****

-Br
LANL2DZ
-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857
-Ag
AG-ECP     3     28
f potential
  5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
  5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
  5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
  5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121






