%nprocshared=20
%mem=4GB
# opt=(calcfc,ts,modredundant,noeigentest) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3

TS

1 1
 Au                -0.01619200   -1.02614200    0.00920200
 P                  2.20434400   -1.51314800   -0.70946100
 C                 -1.95647100   -0.48745000    0.47206500
 H                 -1.98457400    0.26488100    1.25375000
 C                 -2.33215400   -2.16493700    1.95869000
 H                 -1.40515400   -1.93281000    2.46878200
 C                 -3.04801100   -0.34935900   -0.45074400
 C                 -3.30536600   -1.09610500   -1.57093000
 C                  2.45485100   -3.39708100   -0.57454500
 C                  2.36381100   -0.84604800   -2.50329400
 C                 -4.89277300   -2.90754100    0.96104900
 H                 -5.86858500   -3.14408900    0.54212300
 C                 -4.76166300   -1.85032900    1.79364600
 H                 -5.62173500   -1.23836400    2.04768500
 C                 -4.58327400   -0.66129500   -2.23781700
 H                 -4.34683200   -0.15072600   -3.18233000
 H                 -5.20419300   -1.52349100   -2.50819900
 C                 -4.10900500    0.74168300   -0.28223200
 H                 -4.43289000    0.79115400    0.76415900
 C                 -2.48930800   -2.17560900   -2.19090100
 H                 -1.65438100   -2.49249600   -1.56554000
 H                 -3.11298600   -3.04361400   -2.43544500
 H                 -2.08714700   -1.81463800   -3.14747600
 C                 -5.25649500    0.27149500   -1.20924400
 H                 -5.97284500   -0.30367600   -0.61607800
 H                 -5.80463500    1.09216900   -1.67706500
 C                 -3.56794800    2.16136600   -0.63134900
 C                 -3.11987200    2.29007400   -2.08672900
 H                 -3.98170100    2.17444800   -2.74779500
 H                 -2.69295800    3.27817100   -2.27679100
 H                 -2.37551700    1.53377900   -2.34678300
 C                 -4.58732700    3.24503900   -0.27617000
 H                 -4.85890300    3.18007700    0.78167900
 H                 -4.16840500    4.23743600   -0.46834100
 H                 -5.49613100    3.14446400   -0.87583000
 O                 -2.42465100    2.31815900    0.28955800
 C                 -3.46769600   -1.47377600    2.30678100
 C                  0.99996700   -1.02247600   -3.21042700
 H                  0.21242500   -0.43842400   -2.72626700
 H                  1.09476400   -0.66512600   -4.24275200
 H                  0.67630900   -2.06460700   -3.24813700
 C                  2.64290300    0.66426500   -2.36673300
 H                  1.94459900    1.13299600   -1.66631200
 H                  3.65931700    0.86921000   -2.02226000
 H                  2.51311700    1.14368400   -3.34401200
 C                  3.43931100   -1.51008600   -3.38007600
 H                  3.22667000   -2.56656700   -3.56004300
 H                  3.44561400   -1.00666900   -4.35443300
 H                  4.44675400   -1.42076900   -2.97116900
 C                  1.44378000   -4.09433300   -1.50456600
 H                  1.47539500   -5.17389300   -1.31544200
 H                  0.41858300   -3.75354900   -1.32508100
 H                  1.68054300   -3.93793200   -2.55989800
 C                  3.87820700   -3.88684400   -0.89163400
 H                  3.89347400   -4.98070100   -0.81420500
 H                  4.20320000   -3.62421600   -1.89976600
 H                  4.60953500   -3.49965200   -0.17805900
 C                  2.13164400   -3.76271300    0.88980300
 H                  2.82160400   -3.28045400    1.58875200
 H                  1.10921000   -3.48634700    1.16735100
 H                  2.23611100   -4.84699600    1.01456400
 C                  3.58266300   -0.74850500    0.26338900
 C                  3.38435500   -0.02937700    1.46798800
 C                  4.89446000   -0.84706400   -0.24414800
 C                  4.49339600    0.56752100    2.09436900
 C                  5.98088600   -0.25362300    0.39277000
 H                  5.07999600   -1.39151500   -1.15944800
 C                  5.77883500    0.46452300    1.57065400
 H                  4.32912000    1.11896000    3.01540300
 H                  6.97468900   -0.35101300   -0.03385900
 H                  6.61279600    0.93908500    2.07941100
 C                  2.07524800    0.16165800    2.16836000
 C                  1.58636200   -0.81155400    3.05318000
 C                  1.37967500    1.37363800    2.04163100
 C                  0.41670100   -0.58260000    3.78158600
 H                  2.12793100   -1.74367500    3.17741400
 C                  0.20413400    1.59745100    2.76192700
 H                  1.75538500    2.13813000    1.36953700
 C                 -0.28112800    0.61980700    3.63352000
 H                  0.05510800   -1.34076500    4.47077000
 H                 -0.32736200    2.53608700    2.64069100
 H                 -1.19001000    0.79711600    4.20163200
 C                 -1.43320800    3.21948100    0.04248300
 C                 -1.48386300    4.49087600    0.63390200
 C                 -0.31409600    2.83707500   -0.71430600
 C                 -0.42835200    5.38026600    0.46605400
 H                 -2.34737700    4.76162100    1.23076100
 C                  0.74264000    3.71978300   -0.89056000
 H                 -0.28161400    1.83944700   -1.13666900
 C                  0.67210900    4.98364100   -0.29755300
 H                 -0.44712200    6.36375900    0.91877200
 H                  1.61585000    3.43943400   -1.46629000
 N                  1.78938600    5.90919900   -0.46994300
 O                  1.70340100    7.02981300    0.03998500
 O                  2.76815400    5.52640800   -1.11804300
 H                 -3.39106900   -0.60568200    2.95453700
 C                 -2.41849800   -3.51917700    1.29767200
 C                 -3.75946200   -3.81612000    0.58007500
 H                 -2.26752900   -4.24813000    2.10651300
 H                 -1.57685300   -3.65587100    0.61302000
 H                 -4.06682600   -4.85077000    0.77827200
 H                 -3.63950600   -3.76977400   -0.50707700

B 3 5 B

-C -H -O -P -N -F
6-31G(d,p)
****
-Au
LanL2DZ
****

-Au
LanL2DZ
















