%nproc=12
%Mem=20000MB
%Chk=IE10_TSZb_IV_H
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 C                  2.39174800   -1.26401600   -3.04391800
 C                  2.53917100   -2.22419500   -4.04716000
 H                  3.28246200   -2.05997200   -4.82024100
 C                  1.75485700   -3.37856300   -4.06993200
 H                  1.89282300   -4.10846900   -4.86224500
 C                  0.78782500   -3.58787800   -3.08119400
 H                  0.17057500   -4.48089300   -3.09639900
 C                  0.61809300   -2.64621800   -2.07506100
 H                 -0.12512300   -2.80351200   -1.30200500
 C                  1.42217400   -1.48516100   -2.02951800
 C                  2.14885100    0.44210300   -0.58272200
 C                  2.89993800    0.94165600    0.36632200
 H                  3.40239400    1.89822800    0.23107700
 C                  6.46118300    3.50244500   -3.31441900
 H                  6.51864500    4.55930100   -3.04840700
 C                  5.06358000    2.99543800   -3.54119100
 H                  4.54138200    3.64944000   -4.25233700
 H                  5.06595400    1.99638700   -3.98414500
 C                  4.24663500    2.98015300   -2.21392400
 H                  4.23769600    3.99438600   -1.79905000
 H                  4.77416500    2.35304300   -1.48716900
 C                  2.83370700    2.50523700   -2.41407300
 C                  2.45060800    1.19468500   -2.62672800
 H                  1.40942200    1.09517100   -2.92761900
 C                  7.61036400    2.80988700   -3.36960700
 C                  7.73031900    1.34144800   -3.70112700
 H                  8.36464300    1.20240000   -4.58759100
 H                  8.23258200    0.81051300   -2.87985300
 H                  6.77961400    0.83774600   -3.88629200
 C                  8.93253900    3.48758800   -3.09319900
 H                  9.60466500    3.40109900   -3.95835700
 H                  8.81275500    4.55027600   -2.85899100
 H                  9.44944500    3.00671300   -2.25077700
 C                  1.77855600    3.57121500   -2.34401700
 H                  0.77321200    3.19002400   -2.54257500
 H                  1.78481300    4.04802400   -1.35352100
 H                  2.00065800    4.36847800   -3.06735800
 Au                 3.26625300   -0.13965900    2.10056400
 P                  3.70108500   -1.36158300    4.05578500
 C                  4.92937100   -2.70889000    3.83402100
 H                  5.08653000   -3.23899300    4.77930000
 H                  5.87796600   -2.28430300    3.49337800
 H                  4.56759100   -3.41239400    3.07876100
 C                  2.22225600   -2.19303300    4.75866700
 H                  1.46610700   -1.44313800    5.00777400
 H                  2.49363600   -2.74941900    5.66166100
 H                  1.80489500   -2.88164700    4.01842100
 C                  4.36671100   -0.34947300    5.43451700
 H                  4.54904600   -0.97738000    6.31266900
 H                  3.64916300    0.43512300    5.69058900
 H                  5.30368600    0.11971500    5.12153100
 O                  0.30334458   -0.92168895   -0.04106072
 C                 -0.74249344   -0.01788928    0.36659855
 H                 -0.32366268    0.81430323    0.93704204
 H                 -1.27795460    0.36513415   -0.50631951
 H                 -1.40319813   -0.61738663    0.99163109
 C                  4.59900600   -0.32435300   -2.34602400
 H                  5.15311100    0.59050000   -2.12252600
 H                  4.40246600   -0.83643700   -1.39621300
 O                  5.34664000   -1.15003200   -3.23718100
 H                  6.15401600   -1.42881700   -2.77739500
 C                  3.26792200   -0.01929800   -3.06731400
 H                  3.54355300    0.16335100   -4.11513200
 C                  1.22642300   -0.54212000   -0.93377200
 H                  0.98579554    0.07352810   -1.77518501

11 23 F
11 22 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nproc=12
%Mem=20000MB
%Chk=IE10_TSZb_IV_H
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(ts, noeigentest, calcfc, modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

11 23 A
11 22 A

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



