%nproc=20
%Mem=40000MB
%Chk=IE10_TSZd_IVb
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 C                  2.43791500   -1.25104400   -3.10536100
 C                  2.51591900   -2.35559600   -3.96882500
 H                  3.29484500   -2.36658000   -4.72737100
 C                  1.62860300   -3.42536300   -3.88312300
 H                  1.71714800   -4.26152400   -4.57061300
 C                  0.62496600   -3.40446800   -2.91469100
 H                 -0.08278600   -4.22430400   -2.83399900
 C                  0.52550000   -2.31569000   -2.05081500
 H                 -0.25932500   -2.28953900   -1.30440600
 C                  1.42485400   -1.24055800   -2.12292100
 C                  2.32710200    0.73692000   -0.77618500
 C                  3.10394300    1.22045700    0.09999000
 H                  3.90196500    1.94927200    0.06683700
 Au                 2.88264300    0.12126700    1.91557000
 P                  2.78109800   -1.00531100    3.94501200
 C                  4.42635500   -1.33487600    4.68471400
 H                  4.31354500   -1.86712600    5.63476200
 H                  4.94376000   -0.38705100    4.85741700
 H                  5.02004600   -1.94086900    3.99484700
 C                  1.96771200   -2.64407100    3.81472300
 H                  0.95818900   -2.51535500    3.41473600
 H                  1.91333200   -3.11821600    4.80018900
 H                  2.53763800   -3.28087700    3.13271400
 C                  1.84176800   -0.11302500    5.24312700
 H                  1.83981600   -0.69693200    6.16943900
 H                  0.81247400    0.04128900    4.90765600
 H                  2.30390000    0.86072300    5.42617500
 O                  0.46944600   -0.51001600   -0.03001900
 C                 -0.39982900    0.46057000    0.55806200
 H                  0.16214800    1.32669100    0.93083100
 H                 -1.15511100    0.79529700   -0.16538500
 H                 -0.88834600   -0.03762300    1.39705000
 C                  1.13762900   -0.05330200   -1.19788700
 H                  0.47247900    0.63993400   -1.73281000
 C                  2.06822800    1.94477300   -3.42569400
 C                  3.10383300    1.23348400   -2.89121100
 H                  3.86041800    1.79780500   -2.35919200
 C                  1.12624700    1.40362800   -4.48994600
 H                  1.56399800    0.51645200   -4.95584700
 H                  1.06437100    2.17228100   -5.27125400
 C                  1.82629900    3.36329100   -2.99168400
 H                  0.81665600    3.46449500   -2.57464000
 H                  2.54712100    3.69264200   -2.23851500
 H                  1.87914200    4.04451900   -3.85090100
 C                  4.76858800   -0.62242400   -2.49165900
 H                  4.51758300   -0.75368200   -1.42996100
 H                  5.09221200   -1.59724200   -2.88412000
 C                  3.51215400   -0.17827900   -3.26789800
 H                  3.80448500   -0.16294600   -4.32739300
 O                  5.77477400    0.36914500   -2.66924500
 H                  6.55037800    0.10373300   -2.15115000
 C                 -0.28434105    1.04458708   -3.98702356
 H                 -0.36430099   -0.01671453   -3.87681786
 H                 -0.45649623    1.51531282   -3.04167713
 C                 -1.33207123    1.53553403   -5.00330725
 H                 -2.37681274    1.30582784   -5.02880738
 C                 -1.08413510    2.35556768   -6.05337370
 C                  0.34164428    2.87849373   -6.30891529
 H                  0.68003212    3.42443154   -5.45314337
 H                  0.99787980    2.05241065   -6.48735773
 H                  0.33765942    3.52197059   -7.16379636
 C                 -2.23210900    2.76590643   -6.99431898
 H                 -2.69560870    1.88873091   -7.39510713
 H                 -2.95580453    3.33356937   -6.44757995
 H                 -1.84253164    3.36052440   -7.79404328

11 36 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nproc=20
%Mem=40000MB
%Chk=IE10_TSZd_IVb
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(ts, noeigentest, calcfc, modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

11 36 A

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



