%nproc=20
%Mem=40000MB
%Chk=IE10_TSZc_IIIb_2
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
C                  3.29167300    1.11785000   -4.53868400
 H                  3.29387700    2.21758100   -4.53978800
 H                  2.61555100    0.78466400   -5.33907800
 C                  2.76984700    0.62701000   -3.17185700
 H                  3.63968500    0.70252600   -2.50461200
 C                  2.32810500   -0.84198900   -3.13745100
 C                  2.81024200   -1.71985800   -4.12258200
 H                  3.48039900   -1.33859400   -4.88296000
 C                  2.48426200   -3.07512100   -4.12850700
 H                  2.87851100   -3.71884000   -4.90983600
 C                  1.65897200   -3.59363100   -3.13312500
 H                  1.39172800   -4.64636200   -3.12413600
 C                  1.17415400   -2.74382200   -2.14191400
 H                  0.52836900   -3.13474000   -1.36442300
 C                  1.50375200   -1.38108000   -2.12223800
 C                  1.53446500    0.69483900   -0.63089300
 C                  2.10847700    1.39680900    0.26584800
 H                  2.47383500    2.41530000    0.21790100
 Au                 2.53747400    0.31490100    2.03988200
 P                  3.04876800   -0.79679900    4.01771900
 C                  2.39208400   -2.50926900    4.05850700
 H                  2.65618700   -2.99145400    5.00527400
 H                  2.81134800   -3.08090300    3.22608200
 H                  1.30400500   -2.48121400    3.95280400
 C                  2.36825300    0.00379900    5.52130200
 H                  2.77253500    1.01578700    5.61185400
 H                  2.63642200   -0.57810400    6.40914700
 H                  1.27929600    0.06438600    5.44080800
 C                  4.84618700   -0.96585900    4.34160900
 H                  5.00926900   -1.50990500    5.27778500
 H                  5.29892800    0.02685800    4.41315800
 H                  5.31530800   -1.50935800    3.51690300
 O                  0.63159000   -1.34938500    0.12564400
 C                 -0.51701200   -0.99800300    0.90031400
 H                 -0.44315900    0.02673900    1.28634600
 H                 -1.43409100   -1.10290400    0.30558900
 H                 -0.54234800   -1.69481900    1.73979900
 O                  4.61193500    0.61801700   -4.72829400
 H                  4.91188900    0.89215900   -5.60958900
 C                  0.81669200   -0.55000300   -1.03466400
 H                 -0.17286200   -0.24773000   -1.40979100
 C                  0.44847000    1.83770700   -2.93119200
 C                  1.77989700    1.65542500   -2.64396700
 H                  2.27319000    2.51084100   -2.19076300
 C                 -0.26924200    3.02889000   -2.36457200
 H                 -1.11775700    2.69714900   -1.75124100
 H                  0.38062500    3.66220900   -1.75495400
 H                 -0.69305600    3.62633700   -3.18084400
 C                 -0.37351800    0.92584100   -3.80323900
 H                 -1.40317200    0.88284700   -3.42723000
 H                  0.02831900   -0.08898800   -3.80100600
 C                 -0.41403100    1.39083000   -5.29823100
 H                 -0.89816000    0.57390200   -5.84934400
 H                  0.61003400    1.45114300   -5.67383900
 C                 -1.17322400    2.66296500   -5.55127600
 H                 -2.25372500    2.57726700   -5.42517000
 C                 -0.67880300    3.86321400   -5.89843900
 C                 -1.59386400    5.04296300   -6.12644700
 H                 -1.47766900    5.43647200   -7.14576500
 H                 -2.64698700    4.78373800   -5.97795700
 H                 -1.34346300    5.86782200   -5.44493400
 C                  0.78780400    4.17284600   -6.07614900
 H                  1.44127500    3.31222800   -5.91653700
 H                  0.98156700    4.56412700   -7.08391700
 H                  1.09390300    4.95967800   -5.37295500

16 43 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nproc=20
%Mem=40000MB
%Chk=IE10_TSZc_IIIb_2
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(ts, noeigentest, calcfc, modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

16 43 A

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



