%nproc=12
%Mem=20000MB
%Chk=IE10_TSZ_III_H
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 C                  3.18416800    0.53860700   -4.70553100
 H                  3.18119300    1.62673700   -4.84058500
 H                  2.32668300    0.13281000   -5.26004800
 C                  3.04536100    0.20540100   -3.19636100
 H                  4.06755500    0.18089800   -2.80015700
 C                  2.40748200   -1.16850700   -2.97900400
 C                  2.68286600   -2.20822600   -3.87589900
 H                  3.39370600   -2.03475100   -4.67627500
 C                  2.05675400   -3.45079400   -3.76787900
 H                  2.29626400   -4.23409100   -4.48120400
 C                  1.11825900   -3.68410200   -2.75768700
 H                  0.62108600   -4.64588500   -2.67731500
 C                  0.83608500   -2.67668200   -1.84587300
 H                  0.12937100   -2.84582500   -1.04094000
 C                  1.49248400   -1.42900500   -1.92664400
 C                  2.19280900    0.51797100   -0.54466300
 C                  2.98000900    0.96046700    0.40705200
 H                  3.52923600    1.89153800    0.27943400
 C                  6.46977300    3.64101400   -3.06309800
 H                  6.63970400    4.56985300   -2.51639600
 C                  5.02431200    3.32276200   -3.33380900
 H                  4.49854800    4.22852500   -3.66169700
 H                  4.92794300    2.58817400   -4.13554600
 C                  4.32472000    2.77520400   -2.04978200
 H                  4.50171700    3.49454900   -1.23909300
 H                  4.82310800    1.84241900   -1.76772700
 C                  2.84570900    2.57164100   -2.21496200
 C                  2.28435300    1.34106500   -2.52622400
 H                  1.21701000    1.35402900   -2.74773700
 C                  7.53873100    2.89200100   -3.37901900
 C                  7.48305900    1.56626500   -4.10047800
 H                  8.05701700    1.61718100   -5.03666300
 H                  7.96280000    0.78788500   -3.49070000
 H                  6.47306400    1.22464300   -4.33996600
 C                  8.93424300    3.34386900   -3.01765400
 H                  9.55961600    3.43692900   -3.91665900
 H                  8.93684600    4.30805600   -2.49895100
 H                  9.42915200    2.60500500   -2.37186200
 C                  1.97016600    3.75311900   -1.92913900
 H                  0.91411800    3.55310500   -2.12939900
 H                  2.07617400    4.06173400   -0.87922600
 H                  2.28424100    4.61505300   -2.53365800
 Au                 3.26665900   -0.12070400    2.15480100
 P                  3.61292300   -1.31379800    4.14539300
 C                  5.02035200   -2.49128700    4.07820800
 H                  5.12884500   -3.00819600    5.03729700
 H                  5.94128300   -1.94689400    3.85151900
 H                  4.84238700   -3.22578100    3.28765400
 C                  2.18250100   -2.33814700    4.67282800
 H                  1.30911800   -1.69697600    4.82171800
 H                  2.41417800   -2.85979900    5.60736200
 H                  1.95195200   -3.07153500    3.89480800
 C                  3.97087400   -0.24159000    5.59272600
 H                  4.11658600   -0.85053200    6.49089700
 H                  3.13534600    0.44621800    5.75130900
 H                  4.87458300    0.34323600    5.39875900
 O                  0.24781419   -0.75409093   -0.04381602
 C                 -0.93385466    0.07308923   -0.00596696
 H                 -0.68953379    1.06381889    0.38359139
 H                 -1.36533033    0.16512060   -1.00645485
 H                 -1.61934406   -0.44549077    0.66299286
 O                  4.41513100   -0.01846100   -5.16412400
 H                  4.49001600    0.15526900   -6.11640800
 C                  1.24946400   -0.45347200   -0.87465800
 H                  0.75520720    0.34953530   -1.38041435

16 28 F
16 27 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nproc=12
%Mem=20000MB
%Chk=IE10_TSZ_III_H
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(ts, noeigentest, calcfc, modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

16 28 A
16 27 A

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



