%nproc=12
%Mem=20000MB
%Chk=IE10_TSZd_IVb_ADAP
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 C                  4.08624700    4.26095800   -2.55769000
 H                  5.02960900    4.73138100   -2.24869000
 H                  3.33751500    5.05686400   -2.69567800
 C                  3.60614200    3.28358400   -1.46360700
 H                  4.41523400    2.55140300   -1.33934300
 C                  3.37218600    3.96993400   -0.10997600
 C                  3.91563300    5.23955400    0.14725200
 H                  4.50190300    5.74053000   -0.61290900
 C                  3.72615500    5.90214400    1.36007100
 H                  4.16493200    6.88486000    1.50740300
 C                  2.97697500    5.30413100    2.37063600
 H                  2.81773200    5.80697500    3.31970400
 C                  2.43549700    4.04211700    2.14451600
 H                  1.84681200    3.56474900    2.92411100
 C                  2.61956100    3.36945700    0.92792900
 C                  2.65118900    0.96771700    0.10570000
 C                  2.23861200    1.46697200   -2.68704700
 C                  2.34819600    2.57523900   -1.91987800
 H                  1.42554500    3.07838200   -1.64451800
 Au                 3.34765300   -1.11820600    1.79421700
 P                  3.45885700   -2.39503900    3.72968900
 C                  5.17407200   -2.76021400    4.26326700
 H                  5.16029500   -3.36319700    5.17687600
 H                  5.70465400   -1.82315600    4.45270600
 H                  5.69390900   -3.30799800    3.47247200
 C                  2.65714300   -1.59641500    5.17262300
 H                  2.73655400   -2.24423900    6.05163000
 H                  1.60263100   -1.41414200    4.94817800
 H                  3.14633800   -0.64064100    5.37902700
 C                  2.64106500   -4.02640100    3.55788200
 H                  1.58670200   -3.87942900    3.30836300
 H                  2.72044700   -4.58779700    4.49450500
 H                  3.11937900   -4.59063100    2.75265100
 C                  3.32370800   -0.07613100   -0.08534200
 H                  3.84149400   -0.55604200   -0.90266500
 O                  0.57942700    2.20192300    0.43608500
 C                 -0.23039600    1.03228300    0.54577100
 H                 -0.21259500    0.63157000    1.56999000
 H                  0.09581200    0.24910700   -0.15068600
 H                 -1.24685700    1.33905100    0.29350000
 O                  4.28398400    3.51427200   -3.75068900
 H                  4.60493800    4.12766000   -4.42962300
 C                  0.87781100    0.94341100   -3.06945900
 H                  0.06925200    1.55524000   -2.65991200
 H                  0.74971400   -0.08688500   -2.71052900
 C                  3.39471900    0.68051200   -3.23206700
 H                  4.35901600    0.98772100   -2.82507900
 H                  3.44601000    0.82075700   -4.31854100
 H                  3.24589600   -0.39479900   -3.05996200
 C                  1.91932900    2.01583700    0.85350000
 H                  1.91300600    1.60651100    1.87994600
 C                  0.72823604    0.89437870   -4.60139345
 H                  1.37541500    0.14074478   -4.99900546
 H                  0.99096820    1.84514429   -5.01602172
 C                 -0.73093054    0.56162426   -4.96430854
 H                 -1.44376329    0.37405416   -4.18868818
 C                 -1.11526323    0.50555037   -6.26265793
 C                 -2.57645211    0.17208806   -6.61667763
 H                 -2.69850408    0.18816313   -7.67957222
 H                 -2.82052811   -0.80088277   -6.24431400
 H                 -3.22556535    0.89729261   -6.17212127
 C                 -0.09583121    0.77414784   -7.38525036
 H                  0.28127142    1.77128198   -7.29350555
 H                  0.71311345    0.07823352   -7.30643538
 H                 -0.57357216    0.65955084   -8.33579289

16 18 F
17 41 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nproc=12
%Mem=20000MB
%Chk=IE10_TSZd_IVb_ADAP
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(ts, noeigentest, calcfc, modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

16 18 A
17 41 A

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



