%nproc=20
%Mem=40000MB
%Chk=IE10_TSEd_IIb
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 C                  2.80100500   -0.56543500   -3.36767400
 C                  3.03372800   -1.59391000   -4.29529000
 H                  3.92532600   -1.54160100   -4.91540500
 C                  2.16356700   -2.67212500   -4.43846500
 H                  2.37567100   -3.44836900   -5.16788700
 C                  1.02403000   -2.74188600   -3.63737100
 H                  0.33324600   -3.57495800   -3.72924600
 C                  0.76353600   -1.72321000   -2.72215800
 H                 -0.12966900   -1.76366600   -2.11131500
 C                  1.63458700   -0.63411000   -2.57582000
 C                  2.30440100    1.15754200   -0.90703500
 C                  2.93089900    1.46332300    0.14890000
 H                  3.72379600    2.15690100    0.38952100
 Au                 2.46794900   -0.04012300    1.59709300
 P                  2.13124500   -1.63791800    3.24918600
 C                  3.68702000   -2.39936800    3.85058400
 H                  3.46881400   -3.15320600    4.61401200
 H                  4.32966200   -1.62423000    4.27696700
 H                  4.20898400   -2.86896800    3.01234000
 C                  1.09105100   -3.03989300    2.68415600
 H                  0.11056100   -2.66453800    2.37805400
 H                  0.96761900   -3.76724400    3.49314600
 H                  1.56659500   -3.52304500    1.82616300
 C                  1.29732800   -0.99432100    4.74967000
 H                  1.16352400   -1.79958100    5.47927000
 H                  0.32137200   -0.58416600    4.47598900
 H                  1.90403600   -0.19873100    5.19082500
 O                  0.26210700   -0.01881300   -0.69355900
 C                 -0.55542600    0.97370900   -0.07086100
 H                  0.02932600    1.60138500    0.61318000
 H                 -1.04235300    1.60678100   -0.82158300
 H                 -1.31165400    0.42972600    0.49742200
 C                  1.19128000    0.49109700   -1.63910600
 H                  0.69236600    1.25708400   -2.24804600
 C                  2.59463000    2.71841400   -3.39461000
 C                  3.46966200    1.87924600   -2.76659300
 H                  4.14122900    2.32899100   -2.04496400
 C                  2.09876770    3.99611437   -2.75876597
 H                  2.79906833    4.34445878   -1.99518689
 H                  1.18492122    3.70106178   -2.21494846
 C                  1.98720282    2.31968336   -4.71067865
 H                  2.26182748    3.03157822   -5.49990925
 H                  2.30839659    1.32206922   -5.02235577
 H                  0.89093740    2.33300983   -4.64933634
 C                  5.01010600   -0.07119800   -2.34472000
 H                  4.60000300   -0.29878900   -1.35076600
 H                  5.36544300   -1.01327200   -2.78624600
 C                  3.89204500    0.49929100   -3.24263900
 H                  4.34054500    0.62406500   -4.23843600
 O                  6.05725600    0.89046800   -2.26650800
 H                  6.73316200    0.54518000   -1.66283900
 C                  1.73330615    5.17650951   -3.68897756
 H                  1.03536288    4.83748602   -4.46177634
 H                  1.17711197    5.90012494   -3.08208949
 C                  2.92345403    5.84682174   -4.33697138
 H                  3.13005575    5.56649087   -5.37082727
 C                  3.74242208    6.73876246   -3.75303390
 C                  3.59086183    7.22023484   -2.33032334
 H                  2.70063041    6.82918165   -1.83174293
 H                  4.46357490    6.92520451   -1.73390744
 H                  3.54330705    8.31711128   -2.30054836
 C                  4.91627972    7.33184683   -4.49397976
 H                  4.93803175    7.02781957   -5.54514748
 H                  4.88705563    8.42909620   -4.45807705
 H                  5.86375715    7.02781153   -4.02857555

11 36 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nproc=20
%Mem=40000MB
%Chk=IE10_TSEd_IIb
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt=(ts, noeigentest, calcfc, modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

11 36 A

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



