%nprocshared=24
%mem=124GB
#p genecp scrf=(smd,solvent=dichloromethane) nosymm pop=full
empiricaldispersion=gd3 gfinput gfprint m06 scf=(maxcyc=400,xqc)

Title Card Required

2 3
 Co                 0.14822500    0.10761300   -0.09958200
 N                 -0.09956700    1.80691400   -1.01694900
 C                 -1.01853000    1.92341900   -1.98739400
 H                 -1.58576700    1.02459000   -2.22572200
 C                 -1.22965700    3.11893800   -2.65139600
 H                 -1.98563500    3.18165800   -3.42880600
 C                 -0.45271400    4.21672000   -2.29872100
 H                 -0.58862100    5.17289600   -2.79880200
 C                  0.49291300    4.09138700   -1.28888200
 H                  1.08808400    4.94419700   -0.97279400
 C                  0.64873200    2.86694500   -0.64598600
 C                  1.61315900    2.70069000    0.46588900
 C                  2.87553500    3.28631300    0.33867600
 H                  3.11880800    3.80901300   -0.58514600
 C                  3.83049900    3.18791900    1.34569500
 H                  4.80774900    3.64368300    1.20318400
 C                  3.53898700    2.51461400    2.52511700
 H                  4.27753500    2.44165300    3.31992700
 C                  2.28763700    1.93253400    2.69242000
 H                  2.04554200    1.40821600    3.61575800
 C                  1.33801200    2.01578600    1.67351600
 C                  0.79537100   -1.13592700   -1.71175900
 C                  1.83431100   -1.13973000   -0.70075200
 C                  1.26196900   -1.62441200    0.49848600
 C                 -0.13214900   -1.97653400    0.22049100
 C                 -0.39046800   -1.72776300   -1.15064500
 C                  0.99533500   -0.69095300   -3.10653300
 H                  0.05499400   -0.45843400   -3.61676700
 H                  1.48832700   -1.49790900   -3.67036400
 H                  1.65280800    0.18515300   -3.16203800
 C                  3.20802700   -0.62469200   -0.90946600
 H                  3.79636400   -1.34828400   -1.49269500
 H                  3.73505000   -0.45057300    0.03499900
 H                  3.20249400    0.31327700   -1.48096800
 C                  1.93513500   -1.82681500    1.80277300
 H                  2.85532500   -1.23989400    1.89057000
 H                  2.20891500   -2.88756200    1.90533600
 H                  1.28267400   -1.59216400    2.65346700
 C                 -1.09893400   -2.54256600    1.18868700
 H                 -1.12323000   -3.63778200    1.08619100
 H                 -2.11615300   -2.17842500    0.99622500
 H                 -0.83509200   -2.31601100    2.22742100
 C                 -1.70799100   -1.90133100   -1.81201400
 H                 -2.51451500   -1.42859100   -1.23220600
 H                 -1.95783200   -2.96996400   -1.87860200
 H                 -1.72344700   -1.49228600   -2.82670700
 S                 -0.14547600    1.04842200    1.98809700
 C                 -1.57210700    2.24478900    1.84413900
 F                 -1.19530800    3.42250100    1.39352200
 F                 -2.47394000    1.72129900    1.02625100
 F                 -2.10954000    2.38516700    3.03851900

-Co     0
S   1   1.00
7.1760000              1.0000000
S   1   1.00
2.0090000              1.0000000
S   1   1.00
0.8055000              1.0000000
S   1   1.00
0.1070000              1.0000000
S   1   1.00
0.0375000              1.0000000
P   1   1.00
21.3900000              1.0000000
P   1   1.00
2.6500000              1.0000000
P   1   1.00
0.8619000              1.0000000
P   1   1.00
0.0800000              1.0000000
P   1   1.00
0.0230000              1.0000000
D   3   1.00
39.2500000              0.0361541
10.7800000              0.1896744
3.4960000              0.4524981
D   1   1.00
1.0660000              1.0000000
D   1   1.00
0.2606000              1.0000000
F   1   1.00
2.7800000              1.0000000
****
-Ag     0
S   1   1.00
2.9500000              1.0000000
S   1   1.00
2.1490000              1.0000000
S   1   1.00
0.6684000              1.0000000
S   1   1.00
0.0997000              1.0000000
S   1   1.00
0.0347000              1.0000000
P   1   1.00
6.5530000              1.0000000
P   1   1.00
1.5650000              1.0000000
P   1   1.00
0.5748000              1.0000000
P   1   1.00
0.0833000              1.0000000
P   1   1.00
0.0252000              1.0000000
D   2   1.00
3.3910000              0.1396938
1.5990000              0.4744421
D   1   1.00
0.6282000              1.0000000
D   1   1.00
0.2108000              1.0000000
F   1   1.00
1.6110000              1.0000000
****
-I     0
S   2   1.00
0.7242000             -2.9731048
0.4653000              3.4827643
S   1   1.00
0.1336000              1.0000000
P   2   1.00
1.2900000             -0.2092377
0.3180000              1.1035347
P   1   1.00
0.1053000              1.0000000
P   1   1.00
0.0308000              1.0000000
D   1   1.00
0.2940000              1.0000000
****
-N -C -H -O -Cl -S -B -Br -F 0
6-311++g**
****

-CO     0
CO-ECP     2     10
d potential
3
1    434.1076104            -10.0000000
2     78.8402758            -66.7240276
2     19.6037749            -11.7192243
s-d potential
4
0    151.2307582              3.0000000
1    169.6790026             20.1553110
2     64.9909423            413.3762244
2     12.5076287            133.8727705
p-d potential
4
0     92.7319924              5.0000000
1    121.1910183              6.1892353
2     48.6265909            326.3215919
2     11.9966971             73.8788970
-AG     0
AG-ECP     3     28
f potential
5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121
-I     0
I-ECP     3     46
f-ul potential
5
0      1.0715702             -0.0747621
1     44.1936028            -30.0811224
2     12.9367609            -75.3722721
2      3.1956412            -22.0563758
2      0.8589806             -1.6979585
s-ul potential
5
0    127.9202670              2.9380036
1     78.6211465             41.2471267
2     36.5146237            287.8680095
2      9.9065681            114.3758506
2      1.9420086             37.6547714
p-ul potential
5
0     13.0035304              2.2222630
1     76.0331404             39.4090831
2     24.1961684            177.4075002
2      6.4053433             77.9889462
2      1.5851786             25.7547641
d-ul potential
5
0     40.4278108              7.0524360
1     28.9084375             33.3041635
2     15.6268936            186.9453875
2      4.1442856             71.9688361
2      0.9377235              9.3630657


