%nprocshared=24
%mem=124GB
#p genecp scrf=(smd,solvent=dichloromethane) nosymm pop=full
empiricaldispersion=gd3 gfinput gfprint m06 scf=(maxcyc=400,xqc)

Title Card Required

2 1
 Co                 0.08243200    0.30616900   -0.27416900
 N                 -0.38469700    1.78647000   -1.47962100
 C                 -1.35413500    1.75957500   -2.38943200
 H                 -1.99623200    0.88030000   -2.40237100
 C                 -1.53463700    2.81035800   -3.28759800
 H                 -2.33310800    2.75300600   -4.02200000
 C                 -0.68185100    3.90365200   -3.22349000
 H                 -0.79150300    4.72902700   -3.92229700
 C                  0.30592800    3.94474600   -2.24494300
 H                  0.96364700    4.80515300   -2.15370300
 C                  0.42737600    2.86880000   -1.36902000
 C                  1.32520400    2.77657500   -0.24010500
 C                  2.32016100    3.69207300    0.09140500
 H                  2.54392200    4.53871900   -0.55371600
 C                  3.00118300    3.53261700    1.29043300
 H                  3.76129100    4.25609400    1.57633100
 C                  2.69397100    2.46884000    2.18071800
 H                  3.22735700    2.39720900    3.12596200
 C                  1.73682400    1.53643200    1.85416600
 H                  1.49603500    0.72555200    2.53805900
 C                  1.11509600    1.62185600    0.59667800
 C                  1.06732000   -0.69053400   -1.90725300
 C                  1.92444000   -0.70703300   -0.75410500
 C                  1.22280500   -1.39246300    0.29550100
 C                 -0.03570300   -1.84892400   -0.23569600
 C                 -0.13464400   -1.41098500   -1.59102400
 C                  1.42708200   -0.08861000   -3.20916000
 H                  0.55788800    0.05865200   -3.85797600
 H                  2.12440000   -0.76166400   -3.73025300
 H                  1.94309800    0.87165200   -3.08447800
 C                  3.31411300   -0.19816400   -0.72344800
 H                  3.97425400   -0.94155100   -1.19416400
 H                  3.67330200   -0.03279300    0.29746900
 H                  3.41866800    0.73543000   -1.29002500
 C                  1.73957200   -1.75499000    1.63164300
 H                  2.63654900   -1.19143600    1.90461200
 H                  2.00736500   -2.82253800    1.62399600
 H                  0.97859400   -1.62468600    2.41164300
 C                 -0.99449900   -2.72716000    0.46622500
 H                 -0.69190300   -3.77173800    0.29298900
 H                 -2.01576700   -2.61654300    0.08529600
 H                 -0.99207500   -2.57289100    1.55160800
 C                 -1.26486000   -1.71487800   -2.49657700
 H                 -2.23064100   -1.56633400   -1.99503800
 H                 -1.21723700   -2.77352100   -2.79258100
 H                 -1.23918800   -1.11534100   -3.41259500
 S                 -1.55657400    0.37991400    1.14954700
 C                 -2.05555700    2.12132100    1.36689800
 F                 -1.06401600    2.89894700    1.79832800
 F                 -2.53110400    2.66091600    0.24820200
 F                 -3.02307400    2.15272000    2.27759500

-Co     0
S   1   1.00
7.1760000              1.0000000
S   1   1.00
2.0090000              1.0000000
S   1   1.00
0.8055000              1.0000000
S   1   1.00
0.1070000              1.0000000
S   1   1.00
0.0375000              1.0000000
P   1   1.00
21.3900000              1.0000000
P   1   1.00
2.6500000              1.0000000
P   1   1.00
0.8619000              1.0000000
P   1   1.00
0.0800000              1.0000000
P   1   1.00
0.0230000              1.0000000
D   3   1.00
39.2500000              0.0361541
10.7800000              0.1896744
3.4960000              0.4524981
D   1   1.00
1.0660000              1.0000000
D   1   1.00
0.2606000              1.0000000
F   1   1.00
2.7800000              1.0000000
****
-Ag     0
S   1   1.00
2.9500000              1.0000000
S   1   1.00
2.1490000              1.0000000
S   1   1.00
0.6684000              1.0000000
S   1   1.00
0.0997000              1.0000000
S   1   1.00
0.0347000              1.0000000
P   1   1.00
6.5530000              1.0000000
P   1   1.00
1.5650000              1.0000000
P   1   1.00
0.5748000              1.0000000
P   1   1.00
0.0833000              1.0000000
P   1   1.00
0.0252000              1.0000000
D   2   1.00
3.3910000              0.1396938
1.5990000              0.4744421
D   1   1.00
0.6282000              1.0000000
D   1   1.00
0.2108000              1.0000000
F   1   1.00
1.6110000              1.0000000
****
-I     0
S   2   1.00
0.7242000             -2.9731048
0.4653000              3.4827643
S   1   1.00
0.1336000              1.0000000
P   2   1.00
1.2900000             -0.2092377
0.3180000              1.1035347
P   1   1.00
0.1053000              1.0000000
P   1   1.00
0.0308000              1.0000000
D   1   1.00
0.2940000              1.0000000
****
-N -C -H -O -Cl -S -B -Br -F 0
6-311++g**
****

-CO     0
CO-ECP     2     10
d potential
3
1    434.1076104            -10.0000000
2     78.8402758            -66.7240276
2     19.6037749            -11.7192243
s-d potential
4
0    151.2307582              3.0000000
1    169.6790026             20.1553110
2     64.9909423            413.3762244
2     12.5076287            133.8727705
p-d potential
4
0     92.7319924              5.0000000
1    121.1910183              6.1892353
2     48.6265909            326.3215919
2     11.9966971             73.8788970
-AG     0
AG-ECP     3     28
f potential
5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121
-I     0
I-ECP     3     46
f-ul potential
5
0      1.0715702             -0.0747621
1     44.1936028            -30.0811224
2     12.9367609            -75.3722721
2      3.1956412            -22.0563758
2      0.8589806             -1.6979585
s-ul potential
5
0    127.9202670              2.9380036
1     78.6211465             41.2471267
2     36.5146237            287.8680095
2      9.9065681            114.3758506
2      1.9420086             37.6547714
p-ul potential
5
0     13.0035304              2.2222630
1     76.0331404             39.4090831
2     24.1961684            177.4075002
2      6.4053433             77.9889462
2      1.5851786             25.7547641
d-ul potential
5
0     40.4278108              7.0524360
1     28.9084375             33.3041635
2     15.6268936            186.9453875
2      4.1442856             71.9688361
2      0.9377235              9.3630657


