%nproc=24
%mem=122200MB
#p b3lyp/gen opt=(ts,calcfc,noeigentest,maxstep=3) freq empiricaldispersion=GD3 nosymm scrf=(SMD,solvent=toluene) pseudo=(read)

Title Card Required

0 1
 Cu                 0.47383900   -0.42523200   -0.35281000
 N                  1.26880000    0.01758100   -2.22768400
 C                  1.36943200    1.14439200   -2.94886500
 C                  2.39650500   -0.47119300   -4.07582800
 C                  2.07629700    0.88052000   -4.14248300
 H                  2.93946100   -1.10670100   -4.76173300
 H                  2.32362800    1.58001000   -4.92807100
 N                 -0.34374200   -2.28695300   -1.39001000
 C                 -1.47751300   -3.00211700   -1.43800800
 C                 -1.27958100   -4.16984300   -2.21316000
 C                  0.04114300   -4.09751400   -2.63296200
 H                 -2.00539800   -4.93731200   -2.44079000
 H                  0.62864600   -4.76122800   -3.25226100
 N                  2.17620100   -1.58137600    0.04266200
 C                  2.99852100   -1.66629800    1.10001200
 C                  4.10163300   -2.48560200    0.77430600
 C                  3.87852200   -2.87963000   -0.54059300
 H                  4.93317700   -2.75044900    1.41134900
 H                  4.45617800   -3.51178900   -1.20070500
 N                  1.90413900   -0.96697100   -2.91770800
 N                  2.71881400   -2.32193800   -0.95753800
 N                  0.58006200   -2.96186300   -2.12931200
 H                  2.62760800   -3.10479300   -3.07724100
 C                 -0.10964000    0.57878000    1.09846600
 C                 -1.37068100    0.63873800    1.77129600
 O                 -2.10304600   -0.18187400    2.30132700
 C                 -2.91050300    2.13955700    0.54161900
 H                 -2.99219100    1.24981400   -0.08489600
 H                 -2.72000700    2.99071900   -0.12125000
 B                  2.00451500   -2.40044700   -2.33081300
 C                 -4.20573200    2.33872200    1.33569900
 H                 -4.15236700    3.22560300    1.97680900
 H                 -4.40577700    1.46542600    1.96207400
 H                 -5.04551000    2.47422900    0.64435600
 C                 -2.72964700   -2.51051300   -0.81468300
 C                 -3.32162400   -1.31973800   -1.28997700
 C                 -3.34929600   -3.24434500    0.22223900
 C                 -4.53278900   -0.89085900   -0.72767200
 C                 -4.55590000   -2.77823200    0.75754300
 C                 -5.16719700   -1.60563800    0.29345900
 H                 -4.98837100    0.02566100   -1.09610400
 H                 -5.02686100   -3.33798300    1.56364600
 C                  2.66476300   -0.93530400    2.34599800
 C                  3.42800300    0.18953200    2.72893300
 C                  1.53565400   -1.32200500    3.10281200
 C                  3.04638800    0.91225300    3.86687900
 C                  1.19247800   -0.57290100    4.23718300
 C                  1.93518200    0.54421500    4.63763500
 H                  3.62645300    1.78713300    4.15420700
 H                  0.31623200   -0.86390300    4.81210300
 C                  0.80580600    2.40907300   -2.41654300
 C                  1.42125300    3.02472700   -1.30497200
 C                 -0.36080900    2.96550900   -2.98465400
 C                  0.85334700    4.19277700   -0.77787200
 C                 -0.90121700    4.12781200   -2.42056100
 C                 -0.30895200    4.75663300   -1.31701200
 H                  1.32805800    4.66809000    0.07773100
 H                 -1.80954900    4.54880100   -2.84781100
 C                 -2.66671300   -0.48995200   -2.37054700
 H                 -2.29873500   -1.11058000   -3.19417600
 H                 -1.79775700    0.04737700   -1.97643100
 H                 -3.36628600    0.24658000   -2.77668500
 C                 -2.72281400   -4.50714800    0.77098800
 H                 -1.65905200   -4.36343900    0.98985300
 H                 -2.79254500   -5.33665700    0.05781600
 H                 -3.22249300   -4.81778800    1.69353100
 C                 -6.45672300   -1.11777000    0.91077700
 H                 -6.87926800   -0.27910500    0.34902500
 H                 -6.29386100   -0.78202900    1.94254900
 H                 -7.20840000   -1.91495500    0.94718900
 C                  0.68480500   -2.50295400    2.69398300
 H                  1.30028100   -3.37310900    2.44064000
 H                  0.08890900   -2.26367000    1.80759900
 H                 -0.00361700   -2.78439700    3.49583600
 C                  4.63165900    0.62987900    1.92634700
 H                  4.42069500    0.64090400    0.85285800
 H                  5.47930300   -0.04946800    2.07571700
 H                  4.95259200    1.63294600    2.22311200
 C                  1.56043500    1.32355800    5.87652200
 H                  1.77883800    2.39040000    5.76038900
 H                  2.12692500    0.96879400    6.74750100
 H                  0.49694200    1.21515100    6.11131300
 C                 -1.02784700    2.32113700   -4.17855600
 H                 -1.12737800    1.23951000   -4.04871200
 H                 -0.44273600    2.47842300   -5.09263000
 H                 -2.02476600    2.74063200   -4.34433700
 C                  2.65994500    2.43500800   -0.66885100
 H                  3.43635000    2.22998400   -1.41455500
 H                  2.43939500    1.47978000   -0.18082800
 H                  3.07666500    3.11200000    0.08247600
 C                 -0.91839200    6.00692200   -0.72724500
 H                 -1.97764300    5.85691200   -0.48706600
 H                 -0.86624900    6.84467000   -1.43368100
 H                 -0.40289000    6.31033500    0.18916000
 H                  0.63560700    1.23659300    1.56180200
 N                 -1.72506000    1.96703600    1.39300500
 C                 -1.17566600    3.15199800    2.09231900
 H                 -0.26418500    3.48746500    1.58839200
 C                 -0.92137500    2.90764000    3.57693000
 H                 -0.54214400    3.82545900    4.03926500
 H                 -1.84227700    2.61322800    4.09129500
 H                 -0.17472000    2.12429600    3.73186600
 H                 -1.91421200    3.94837100    1.96567000

-H -B -C -N -O 0
6-31+g(d,p)
****
-Cu 0
SDD
*****

-Cu 0
SDD


