%nproc=28
%mem=122200MB
#p b3lyp/gen opt=(ts,calcfc,noeigentest) freq empiricaldispersion=GD3 nosymm scrf=(SMD,solvent=toluene) pseudo=(read)

Title Card Required

0 1
 29           0        1.206168    0.488883    0.679189
  7           0        2.123471    2.358355    0.819977
  6           0        1.767793    3.642758    0.612538
  6           0        3.901967    3.634803    1.229857
  6           0        2.877238    4.485149    0.847695
  1           0        4.919926    3.838705    1.531272
  1           0        2.904387    5.561796    0.766295
  7           0        3.097614   -0.551249    0.256212
  6           0        3.477122   -1.660588   -0.402795
  6           0        4.869369   -1.852729   -0.253105
  6           0        5.293248   -0.796183    0.540777
  1           0        5.467096   -2.650031   -0.670981
  1           0        6.271955   -0.537485    0.920627
  7           0        1.954593    0.254422    2.844501
  6           0        1.458960   -0.047540    4.054818
  6           0        2.442581    0.176834    5.048356
  6           0        3.554259    0.629172    4.351694
  1           0        2.345723    0.021735    6.113260
  1           0        4.537975    0.922626    4.691542
  7           0        3.433221    2.367023    1.205649
  7           0        3.236821    0.666810    3.035838
  7           0        4.214825   -0.032372    0.831437
  1           0        5.204694    1.425669    2.227699
  6           0       -0.335811   -0.155411   -0.119819
  6           0       -1.639296   -0.419205    0.559956
  8           0       -2.217038    0.528370    1.130033
  6           0       -3.480511   -1.913129    1.097737
  1           0       -3.672467   -1.102701    1.800360
  1           0       -3.470968   -2.843474    1.668719
  5           0        4.107746    1.124917    1.841498
  6           0       -4.564040   -1.952808    0.017163
  1           0       -4.397782   -2.773091   -0.689624
  1           0       -4.579350   -1.015283   -0.543571
  1           0       -5.548110   -2.097092    0.478102
  6           0        2.508458   -2.505383   -1.144073
  6           0        1.899757   -2.014227   -2.320781
  6           0        2.220209   -3.810989   -0.691663
  6           0        0.985717   -2.822757   -3.005442
  6           0        1.312237   -4.594894   -1.417151
  6           0        0.673757   -4.115764   -2.566158
  1           0        0.503827   -2.432834   -3.899274
  1           0        1.083258   -5.597317   -1.061795
  6           0        0.084389   -0.575133    4.224649
  6           0       -0.856871    0.128082    5.011075
  6           0       -0.271179   -1.807981    3.633942
  6           0       -2.139666   -0.407568    5.179703
  6           0       -1.558406   -2.316922    3.846936
  6           0       -2.510505   -1.631037    4.607942
  1           0       -2.867052    0.144419    5.772393
  1           0       -1.825126   -3.270595    3.399431
  6           0        0.383962    4.075861    0.300897
  6           0       -0.665255    3.797641    1.209445
  6           0        0.126138    4.852815   -0.854460
  6           0       -1.952454    4.280741    0.928394
  6           0       -1.176537    5.304023   -1.098521
  6           0       -2.229638    5.038232   -0.214482
  1           0       -2.755691    4.060186    1.627796
  1           0       -1.371434    5.883055   -1.999228
  6           0        2.256368   -0.649618   -2.854411
  1           0        3.300182   -0.624709   -3.193441
  1           0        2.158547    0.115362   -2.082527
  1           0        1.617837   -0.375090   -3.698106
  6           0        2.869717   -4.381807    0.549442
  1           0        2.918926   -3.646187    1.356398
  1           0        3.898678   -4.703201    0.347221
  1           0        2.315643   -5.253386    0.911133
  6           0       -0.369502   -4.941681   -3.279237
  1           0       -1.377872   -4.647848   -2.957617
  1           0       -0.254301   -6.009344   -3.066186
  1           0       -0.322972   -4.798897   -4.364277
  6           0        0.706207   -2.588474    2.785951
  1           0        1.697990   -2.627054    3.247733
  1           0        0.837567   -2.121595    1.804640
  1           0        0.357212   -3.612868    2.630879
  6           0       -0.506474    1.434575    5.687926
  1           0        0.128721    2.062695    5.058962
  1           0        0.041017    1.260938    6.622783
  1           0       -1.411768    1.997109    5.936295
  6           0       -3.909352   -2.173708    4.782760
  1           0       -4.276708   -2.014411    5.802709
  1           0       -3.953777   -3.246251    4.567721
  1           0       -4.611012   -1.671960    4.103903
  6           0        1.220890    5.224556   -1.829351
  1           0        1.976676    4.441143   -1.924985
  1           0        1.742375    6.132316   -1.501292
  1           0        0.803824    5.424551   -2.821133
  6           0       -0.446803    3.005170    2.474708
  1           0        0.542678    3.182823    2.902931
  1           0       -0.536848    1.933125    2.275776
  1           0       -1.203817    3.262277    3.221390
  6           0       -3.613116    5.584564   -0.476737
  1           0       -4.375905    5.029282    0.076689
  1           0       -3.863813    5.546149   -1.542403
  1           0       -3.680552    6.635630   -0.167096
  1           0       -0.319212   -0.556099   -1.138187
  7           0       -2.145059   -1.684385    0.536542
  6           0       -1.510992   -2.745541   -0.271246
  1           0       -1.843087   -2.660983   -1.314116
  6           0       -1.788932   -4.155448    0.245494
  1           0       -1.206602   -4.863382   -0.349073
  1           0       -1.487091   -4.263379    1.291309
  1           0       -2.843359   -4.432779    0.155573
  1           0       -0.430985   -2.585774   -0.260194
  7           0       -0.167434    1.978852   -2.120666
  7           0        0.852600    2.170931   -2.574495
  6           0       -1.340492    1.685461   -1.609132
  6           0       -2.214110    0.849792   -2.475608
  8           0       -1.704510    0.005382   -3.235390
  7           0       -3.557212    1.026633   -2.364725
  6           0       -4.198736    2.202614   -1.752269
  1           0       -3.457065    2.994590   -1.646961
  1           0       -4.943326    2.571807   -2.467191
  6           0       -4.429088    0.125465   -3.134665
  1           0       -5.396949    0.101259   -2.625843
  1           0       -4.004018   -0.879575   -3.089103
  6           0       -4.600366    0.565422   -4.590909
  1           0       -5.283538   -0.116156   -5.110686
  1           0       -5.018630    1.576303   -4.653259
  1           0       -3.637452    0.553004   -5.109727
  6           0       -4.858363    1.905153   -0.406530
  1           0       -4.119910    1.540345    0.311638
  1           0       -5.319065    2.817960   -0.012902
  1           0       -5.647033    1.152050   -0.508958
  1           0       -1.636599    2.269515   -0.749201

-H -B -C -N -O 0
6-31+g(d,p)
****
-Cu 0
SDD
*****

-Cu 0
SDD


