%nprocshared=24
%mem=96GB
%chk=TD_A-1.chk
#p td=(nstates=15,singlet) genecp scrf=(smd,solvent=chloroform) nosymm um06 gfinput gfprint scf=(maxcyc=400,xqc) pop=full cphf=maxinv=12000

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0 1
 Pd                -3.85790700    0.08792700    2.00934100
 C                 -5.16763300   -1.22171800   -0.37740800
 C                 -5.25778900    0.99657600   -0.51097700
 C                 -6.13234000   -0.91027900   -1.45169700
 C                 -6.18652000    0.48126000   -1.53750400
 C                 -6.90251000   -1.71620200   -2.27502200
 C                 -7.01095700    1.11889800   -2.45052400
 C                 -7.73387100   -1.08129800   -3.20185900
 H                 -6.86040800   -2.80215600   -2.20161500
 C                 -7.78709000    0.31359000   -3.28880800
 H                 -7.05101400    2.20566100   -2.51163200
 H                 -8.35314600   -1.68157900   -3.86724800
 H                 -8.44663300    0.77753400   -4.02104000
 N                 -3.61081800   -2.00089900    2.01693400
 C                 -4.09335400   -2.81243400    1.03109600
 C                 -2.78333300   -2.54374500    2.93974700
 C                 -3.75959800   -4.18519500    1.02475100
 C                 -2.41063600   -3.87176200    2.96113900
 H                 -2.40305000   -1.86457800    3.69628100
 C                 -2.91943500   -4.71951600    1.97530100
 H                 -4.18910900   -4.79287400    0.23181100
 H                 -1.73810500   -4.22778100    3.73766700
 H                 -2.66104800   -5.77687500    1.95526600
 N                 -3.76755200    2.17369200    1.75608100
 C                 -2.96978400    2.88079600    2.58966900
 C                 -4.32102200    2.82455900    0.69166700
 C                 -2.70039800    4.22641800    2.44914000
 H                 -2.52534700    2.32590100    3.40967600
 C                 -4.10101300    4.20991400    0.52369000
 C                 -3.29212600    4.91336600    1.38772100
 H                 -2.04356600    4.71887100    3.16189200
 H                 -4.58747200    4.68720500   -0.32376000
 H                 -3.11918500    5.97824300    1.24100300
 C                 -3.49104700    0.22861500    4.01995700
 H                 -2.41204900    0.26519500    4.24044500
 H                 -3.97695100    1.13551500    4.40788000
 H                 -3.94110700   -0.63797200    4.52589600
 N                 -5.12783700    2.26486300   -0.26665900
 N                 -4.93402900   -2.43672400    0.01463500
 N                 -4.63460200   -0.05712800    0.08795200

 -C -H -N -O
6-31+g(d)
******
Pd     0 
S   1   1.00
      2.7870000              1.0000000        
S   1   1.00
      1.9650000              1.0000000        
S   1   1.00
      0.6243000              1.0000000        
S   1   1.00
      0.1496000              1.0000000        
S   1   1.00
      0.0436000              1.0000000        
P   1   1.00
      5.9990000              1.0000000        
P   1   1.00
      1.4430000              1.0000000        
P   1   1.00
      0.5264000              1.0000000        
P   1   1.00
      0.0899000              1.0000000        
P   1   1.00
      0.0262000              1.0000000        
D   2   1.00
      6.0910000              0.0376146        
      1.7190000              0.5200479        
D   1   1.00
      0.6056000              1.0000000        
D   1   1.00
      0.1883000              1.0000000        
F   1   1.00
      1.4720000              1.0000000  
****

PD     0
PD-ECP     3     28
f-ul potential
  5
0    598.3336444             -0.0563177        
1    162.4298290            -20.1288036        
2     51.5714771           -105.8197923        
2     16.4888260            -42.5733345        
2      5.8287656             -3.6165086        
s-ul potential
  5
0     73.3806304              3.0003651        
1     14.7550438             32.4350093        
2     17.8350204            459.0830383        
2     12.7111477           -868.0629029        
2      9.3292063            514.4726098        
p-ul potential
  5
0     55.6689877              4.9593099        
1     64.2337771             21.1711029        
2     17.6254952            605.0560092        
2     11.9058155           -726.9641846        
2      8.5100832            396.3274883        
d-ul potential
  5
0     49.9994728              3.0508745        
1     39.7477547             22.2506580        
2     11.4321366            674.8357698        
2      9.1790080          -1040.8554048        
2      7.5624429            505.9375147  




