%nprocshared=24
%mem=96GB
%chk=B-3-O2.chk
#p opt freq=noraman scrf=(solvent=chloroform,smd) nosymm cphf=maxinv=12000 m06/genecp gfinput gfprint pop=full scf=(maxcyc=400,xqc)

Title Card Required

0 3
 Pt                -3.98044400    0.09203300    1.43116800
 C                 -5.53063800   -1.28536700   -0.64968500
 C                 -5.68914100    1.06859100   -0.88329300
 C                 -6.31185500   -0.99936200   -1.73232500
 C                 -6.41114100    0.47514400   -1.87865600
 C                 -6.99802900   -1.83348000   -2.67665800
 C                 -7.18947700    1.00973800   -2.95882000
 C                 -7.71772300   -1.26587200   -3.67588500
 H                 -6.92010600   -2.92433300   -2.56221600
 C                 -7.81421600    0.16716400   -3.81810000
 H                 -7.25858000    2.10239500   -3.06107000
 H                 -8.25244200   -1.88470200   -4.41197000
 H                 -8.41661300    0.55342900   -4.65393100
 N                 -3.61059900   -1.79502000    1.94336700
 C                 -4.10849800   -2.82557800    1.23272700
 C                 -2.85172900   -2.09549500    3.01543000
 C                 -3.87519300   -4.17506200    1.55485600
 C                 -2.56233200   -3.41239200    3.41739700
 H                 -2.45650000   -1.23213100    3.57993500
 C                 -3.08673800   -4.46780500    2.66916400
 H                 -4.30673000   -4.97484500    0.93965500
 H                 -1.93765300   -3.59825200    4.30034600
 H                 -2.88180600   -5.51028600    2.95133000
 N                 -3.71469800    2.03565900    1.76552700
 C                 -2.97603400    2.47471700    2.80310300
 C                 -4.26600500    2.96763100    0.96366600
 C                 -2.75951700    3.83691500    3.08031300
 H                 -2.53587900    1.69020900    3.44413100
 C                 -4.10730100    4.35194100    1.15871100
 C                 -3.33857900    4.78872000    2.23900800
 H                 -2.14813600    4.13758800    3.94063700
 H                 -4.58008000    5.06654200    0.47300600
 H                 -3.19084400    5.86229600    2.42337400
 C                 -5.13372264    0.27928625    3.21247795
 H                 -4.47961508    0.31912976    4.05832405
 H                 -5.71487279    1.17662901    3.16843639
 H                 -5.78594410   -0.56384789    3.30538283
 N                 -5.06494500    2.45232200   -0.15751700
 N                 -4.93129000   -2.46059800    0.07053000
 N                 -5.06896200    0.00224300   -0.01872600
 O                 -2.03145596   -0.16119189    2.02860587
 O                 -2.66542947   -0.13015992    3.00145178

 -C -H -N -O
6-31+g(d)
******
Pt     0 
S   1   1.00
      2.5470000              1.0000000        
S   1   1.00
      1.6140000              1.0000000        
S   1   1.00
      0.5167000              1.0000000        
S   1   1.00
      0.2651000              1.0000000        
S   1   1.00
      0.0580000              1.0000000        
P   1   1.00
      2.9110000              1.0000000        
P   1   1.00
      1.8360000              1.0000000        
P   1   1.00
      0.5982000              1.0000000        
P   1   1.00
      0.0996000              1.0000000        
P   1   1.00
      0.0290000              1.0000000        
D   1   1.00
      1.2430000              1.0000000        
D   1   1.00
      0.4271000              1.0000000        
D   1   1.00
      0.1370000              1.0000000        
F   1   1.00
      0.9930000              1.0000000
****

PT     0
PT-ECP     4     60
g-ul potential
  5
1    728.9394056             -0.1619268        
2    320.6567800          -1320.2873852        
2     52.8680174           -298.3178135        
2     12.0280128            -87.5837065        
2      3.5238913             -8.1493274        
s-ul potential
  6
0    409.4437358              2.7334218        
1    274.5419231             59.7024329        
2    127.5658570            891.4589550        
2     32.9036631            368.4467656        
2      5.0593880            238.0263090        
2      4.1506556           -107.0556454        
p-ul potential
  4
0    466.1728892              1.8878568        
1    120.7888259             76.0138629        
2     36.4118791            343.5511116        
2      5.6985408            119.4911786        
d-ul potential
  5
0    249.5650763              2.9343678        
1    126.6678585             59.3306571        
2     63.1430586            452.4445194        
2     17.9059470            210.4769479        
2      4.2239373             58.6254112        
f-ul potential
  5
0    121.8158799              3.9534253        
1     60.8757030             53.8555182        
2     31.4767147            247.4305133        
2      9.8811751            127.8187976        
2      2.7319874             15.3772046




