%nprocshared=12
%mem=120GB
%chk=POPh3_bb_m06
#p M06/genecp sp nosymm scf(maxcyc=400,XQC) gfinput gfprint pop=full scrf(smd,solvent=benzene)

P(OPh)3

0 1
 P                  0.05474900    0.90489500   -0.44652600
 O                  0.64342000   -0.60786000   -0.82644200
 O                  0.94272400    1.11446300    0.94879500
 O                  1.06662000    1.76637800   -1.45300800
 C                  0.01312700   -1.72907500   -0.29663100
 C                 -0.73007700   -2.54397400   -1.15185200
 C                  0.16278100   -2.05081300    1.05461200
 C                 -1.32916000   -3.69842500   -0.64656100
 H                 -0.82579200   -2.26338900   -2.19610800
 C                 -0.44617000   -3.20591600    1.54924600
 H                  0.75769000   -1.40247600    1.68855500
 C                 -1.19129100   -4.03141200    0.70386400
 H                 -1.90730300   -4.33643000   -1.30943700
 H                 -0.33216300   -3.46205500    2.59914300
 H                 -1.66017900   -4.93034700    1.09382600
 C                  0.67727200    1.98896400   -2.76980600
 C                  0.69664600    0.94517700   -3.69817600
 C                  0.31228500    3.28166900   -3.14862900
 C                  0.34112000    1.20759800   -5.02276000
 H                  0.99803500   -0.04458600   -3.37305300
 C                 -0.03557600    3.53214200   -4.47648900
 H                  0.30804800    4.06854200   -2.40086000
 C                 -0.02457600    2.49719000   -5.41581400
 H                  0.35549400    0.39995600   -5.74966700
 H                 -0.31893700    4.53751600   -4.77588300
 H                 -0.29733400    2.69583500   -6.44836100
 C                  0.71010600    2.24047200    1.73194900
 C                  1.15885600    3.49555500    1.31355300
 C                  0.06210100    2.08011100    2.95756100
 C                  0.94954900    4.60171900    2.13956200
 H                  1.66960400    3.58235400    0.36078800
 C                 -0.13637800    3.19245300    3.77631200
 H                 -0.27366800    1.09029500    3.25063500
 C                  0.30398700    4.45508100    3.36966600
 H                  1.29756500    5.58036900    1.82016800
 H                 -0.63912600    3.07175000    4.73201900
 H                  0.14657300    5.31887900    4.00926700

P O C H 0
6-311+G(d,p)
****









