AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    Ta=2.025
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1        Ta      2.167140      1.411194      3.127928 
      2         H      1.653070      0.448921      0.882608 
      3         H      4.433110      2.269569      3.990218 
      4         O      0.837661      2.405690      4.210896 
      5         O      4.066217      1.635537      3.339810 
      6         O      1.875676      0.066191      4.509056 
      7         H      0.586591      3.244614      3.774994 
      8         O      1.766481      0.054580      1.771571 
      9         O      1.884836      2.820025      1.791027 
end

charge -2

geometry
end

