"$ADFBIN/adf" <<eor

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

AnalyticalFreq
End

SCANFREQ -1000 0

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

XC
  GGA PBE
end

atoms
V 3.520557 2.114522 9.525269
V 4.132492 5.398836 9.748082
V 3.544158 6.603713 12.849194
O 3.945043 6.613401 8.627352999999999
O 5.739314 5.201895 10.087177
O 2.559598 1.229432 8.502483
O 5.074461 1.557459 9.450557
O 3.187327 5.800853 11.257157
O 4.576612 7.88156 12.632468
O 4.304345 5.343482 13.978264
O 2.106175 7.152277 13.46575
O 3.42465 3.860093 9.038663
O 2.858868999999999 1.950434 11.252095
V 1.687671 1.074761 15.674357
V 2.767424 3.71449 17.410982
V 5.017383 5.554357 15.665256
O 2.730778 3.877217 19.066759
O 1.544239 4.599528 16.739104
O 2.063689 -0.534246 15.757095
O 0.049652 1.268974 15.817734
O 4.390008000000001 4.262367 16.791827
O 4.662782 7.058196 16.257891
O 2.576366 1.930983 16.999192
O 6.66671 5.372451 15.578185
V 3.536985 1.657812 12.866872
O 4.244381 0.1921 12.922771
O 4.817007 2.836548 13.265606
O 2.206689 1.769903 14.020018
H 4.542505 3.796566 13.465534
end

charge -6

geometry
end

eor
