AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1         O     -0.000031      0.000013     -0.000004 
      2         V     -0.897561     -1.697095      1.338802 
      3         V      1.910075      0.057372      1.330033 
      4         V      0.897567      1.697092     -1.338816 
      5         V     -1.910063     -0.057380     -1.330050 
      6         V     -1.005904      1.613209      1.355990 
      7         V      1.005876     -1.613231     -1.356013 
      8         O      2.376798      1.178548     -0.037751 
      9         O     -0.689936      1.354498     -2.173999 
     10         O     -2.376779     -1.178524      0.037745 
     11         O      0.689912     -1.354491      2.174012 
     12         O     -2.197271      1.468676     -0.039554 
     13         O      0.820978      1.286203      2.153014 
     14         O      2.197214     -1.468662      0.039573 
     15         O     -0.820966     -1.286214     -2.153027 
     16         O     -1.538780      0.076811      2.169549 
     17         O      0.169372      2.657443      0.026482 
     18         O      1.538768     -0.076811     -2.169534 
     19         O     -0.169355     -2.657470     -0.026484 
     20         O     -1.690942     -2.809866      2.307476 
     21         O     -3.269137      0.062598     -2.301114 
     22         O      1.690991      2.809862     -2.307461 
     23         O      3.269118     -0.062594      2.301121 
     24         O      1.582837     -2.865241     -2.307019 
     25         O     -1.582781      2.865252      2.307031 
end

charge -8

geometry
end

