AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

ScanFreq -1000 0

XC
  Dispersion Grimme3
  GGA PBE
end

atoms
      1         O      5.070878      7.145596     10.890283 
      2         O      3.910652      4.780367      6.260901 
      3         V      4.671108      6.700580      6.400913 
      4         O      8.078855      4.647152      8.348328 
      5         O      6.293632      5.796066      6.666961 
      6         O      5.305571      8.200564      7.227878 
      7         O      4.745647      7.053344      4.843157 
      8         V      3.724339      4.120921      7.800856 
      9         V      5.680394      2.786704      9.899970 
     10         O      7.215165      2.272575      9.778000 
     11         O      3.685269      3.758331      9.903573 
     12         O      2.088800      4.989829      8.254668 
     13         O      5.279097      2.581391     11.647227 
     14         V      5.334701      8.053376      9.048695 
     15         V      2.491184      6.926996      8.583913 
     16         O      6.877611      6.986562      8.997079 
     17         O      5.923843      9.455207      9.544241 
     18         V      4.446635      5.593388     10.682867 
     19         O      2.626601      6.086187     10.400531 
     20         O      4.695336      1.391339      9.317978 
     21         V      1.568980      4.399032     10.106617 
     22         V      2.836987      1.660546      9.435623 
     23         O      3.100809      2.568326      7.594035 
     24         O      0.091248      5.067647     10.135363 
     25         O      1.293150      2.729432      9.486988 
     26         O      2.865844      1.514495     11.255352 
     27         O      2.246918      0.260787      8.939826 
     28         V      6.602598      5.314668      8.377266 
     29         O      0.955379      7.442974      8.705198 
     30         O      4.485705      5.955978      8.580151 
     31         O      5.544160      3.629807      8.083535 
     32         O      3.475208      8.324210      9.165219 
     33         V      3.500689      3.013564     12.083839 
     34         O      4.261144      4.933777     12.223851 
     35         O      1.877129      3.919928     11.817106 
     36         O      3.425114      2.662649     13.640910 
     37         O      6.081962      4.726164     10.229399 
     38         O      2.891446      7.134158      6.835971 
end

charge -6

geometry 
Iterations 125
End

