AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

ScanFreq -1000 0

XC
  Dispersion Grimme3
  GGA PBE
end

atoms
      1         H      5.666044      6.539866     11.228545 
      2         V      5.334701      8.053376      9.048695 
      3         H      2.774817      8.538547      8.445494 
      4         H      7.703999      6.948407      9.612357 
      5         O      5.923843      9.455207      9.544241 
      6         O      5.308711      8.184694      7.424201 
      7         O      6.954472      6.933418      8.994507 
      8         H      7.176412      6.246728      8.344158 
      9         O      5.083630      7.189471     10.801274 
     10         H      4.350634      7.320944     11.425121 
     11         O      3.389007      8.336765      9.170621 
     12         H      2.836256      8.304947      9.968874 
end

charge 1

geometry 
Iterations 125
End

