"$ADFBIN/adf" <<eor

AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

ScanFreq -1000 0

XC
  Dispersion Grimme3
  GGA PBE
end

atoms
V 4.618715 2.584854 11.836812
V 3.485005 5.422253 10.389128
V 3.194616 6.949046 13.291972
O 2.573769 5.633397 9.011568
O 4.947242 6.181801 10.218254
O 4.55707 1.027992 11.253062
O 6.197797 3.059740999999999 11.972885
O 2.56606 6.134549999999999 11.803866
O 3.735972 8.464266 12.91742
O 4.537724 5.976774 14.002002
O 1.926676 7.07067 14.403563
O 3.717478 3.637061 10.648256
O 3.834344 2.631837 13.490573
V 2.229851 2.183668 14.167475
V 2.485818 4.335881 16.893404
V 5.305199 5.69847 15.619057
O 2.183222 3.880609 18.435599
O 1.552465 5.821488 16.595925
O 2.191199 0.54899 14.453483
O 1.006164 2.579794 13.12846
O 4.21521 4.636872 16.698797
O 5.529904 7.146067 16.388465
O 1.96392 3.053487 15.798868
O 6.761057999999999 4.940691 15.434231
H 1.707962 6.276226 15.666245
end

charge -5

geometry 
End

eor
