"$ADFBIN/adf" <<eor

AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

ScanFreq -1000 0

XC
  Dispersion Grimme3
  GGA PBE
end

atoms
V 3.346821 2.332556 12.041744
V 4.397811 5.183924 10.621069
V 3.208469 7.495273999999999 12.751495
O 4.5727 5.606692 9.016824
O 5.859208999999999 5.31217 11.393775
O 2.758975 0.923492 11.37441
O 4.686437 1.997787 12.958954
O 3.161898 6.267977 11.39595
O 4.045115 8.848767000000002 12.255879
O 4.044271 6.831768 14.222833
O 1.642948 7.913788 13.102122
O 3.769965 3.466965 10.678618
O 2.04116 3.101852 13.049451
O 2.416585 6.828210999999999 16.58454
V 1.869369 3.300558 14.862828
V 3.655434 6.038768 15.815549
O 1.887015 1.810199 15.608386
O 0.425116 4.041331 15.157904
O 5.026322 6.100185 16.766205
O 3.237779 4.286154 15.550857
end

charge -5

geometry 
End

eor
