"$ADFBIN/adf" <<eor

AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    V=1.908
  SubEnd
end

ScanFreq -1000 0

XC
  Dispersion Grimme3
  GGA PBE
end

atoms
V       0.31201398       5.92585694       6.31357575
V      -0.82243600       1.73103360       3.97303317
V      -0.03057013       2.94327531       7.00230872
V       0.57843684       4.75457760       3.48024284
O      -1.33853893       2.30645638       7.86464900
O       2.18978902       4.74127093       2.98261391
O      -0.17028152       4.67495964       7.66509517
O       0.23916369       2.83218709       3.08312276
O       0.14357875       4.16237501       5.36928110
O      -0.89744166       7.07228818       6.65626685
O      -0.78099461       0.21234922       3.20263544
O       1.81082170       6.44830557       6.90600769
O      -2.41873075       2.30891924       4.02111848
O      -0.15132434       1.54341053       5.60263651
O       0.51507610       6.32948709       4.47090440
O       1.41365882       2.41081221       7.68795664
O      -0.41352195       5.27453847       2.21316855
H       0.67840148       2.43350299       2.67278690
end

charge -5

geometry 
End

eor
