AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    Nb=2.025
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1        Nb      1.952298      1.623523      3.120509 
      2         H      1.434170      0.364942      0.406968 
      3         H      4.965229      1.910458      3.635114 
      4         O      1.847678      0.132766      4.552849 
      5         O      3.983818      1.816994      3.467490 
      6         H      1.797137     -0.587407      5.244800 
      7         H     -0.413612      2.686024      4.008069 
      8         O      1.253881      1.054613      1.108288 
      9         O      0.567904      2.772737      4.178680 
end

charge 1

geometry
end

