AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    Nb=2.025
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1         O      5.090736      7.131142     10.839545 
      2         O      3.876971      4.811448      6.260613 
      3        Nb      4.643880      6.706384      6.370309 
      4         O      8.105967      4.719358      8.232096 
      5         O      6.242892      5.810199      6.633096 
      6         O      5.274787      8.183224      7.223416 
      7         O      4.694218      7.090155      4.810666 
      8        Nb      3.714623      4.141316      7.801325 
      9        Nb      5.707021      2.777262      9.852679 
     10         O      7.196761      2.174561      9.761799 
     11         O      3.699928      3.784192      9.875424 
     12         O      2.072997      5.006440      8.272828 
     13         O      5.280184      2.580983     11.598289 
     14        Nb      5.333185      8.058247      9.044955 
     15        Nb      2.465956      6.936717      8.584484 
     16         O      6.851605      6.983310      8.944437 
     17         O      5.925988      9.473355      9.521546 
     18        Nb      4.457443      5.574402     10.646340 
     19         O      2.635803      6.082787     10.396382 
     20         O      4.666875      1.410468      9.286304 
     21        Nb      1.566886      4.419388     10.118928 
     22        Nb      2.830222      1.661590      9.402132 
     23         O      3.081929      2.584856      7.606851 
     24         O      0.069372      5.001040     10.220303 
     25         O      1.320718      2.734921      9.501846 
     26         O      2.899342      1.534281     11.223004 
     27         O      2.239109      0.245453      8.926477 
     28        Nb      6.609535      5.303565      8.334400 
     29         O      0.976086      7.539105      8.678657 
     30         O      4.469229      5.937293      8.569410 
     31         O      5.535638      3.635632      8.051054 
     32         O      3.504060      8.308746      9.160516 
     33        Nb      3.536653      3.007915     12.077638 
     34         O      4.295437      4.905790     12.187452 
     35         O      1.932111      3.904738     11.814639 
     36         O      3.485920      2.622940     13.636940 
     37         O      6.097736      4.711565     10.172934 
     38         O      2.893573      7.138290      6.845299 
end

charge -6

geometry
end

