AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    Nb=2.025
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1         O     -2.904799      0.903234      0.070792 
      2         O      4.683502     -5.811287     -0.690674 
      3         O     -7.977109      0.112021     -1.232131 
      4         O      3.281848     -3.328101      5.151306 
      5         O     -0.446950     -5.167907     -0.761058 
      6         O      7.341217     -5.716557      3.385079 
      7         O      1.354818     -2.250478      3.555021 
      8         O      7.539449     -5.859563     -1.670141 
      9         O      6.031686     -8.406401      3.511451 
     10         O      4.649733     -5.795897      4.164670 
     11        Nb      3.394526     -5.539756      0.708704 
     12        Nb      4.335275     -3.919200      3.788164 
     13         H      1.991639     -2.532338      4.280706 
     14        Nb      2.016157     -2.794879      1.775556 
     15         O      6.113574     -3.328055      4.191797 
     16        Nb     -3.759969     -0.572081      0.598204 
     17        Nb     -6.675972     -1.685326      1.775377 
     18         O     -4.316402     -1.461724     -1.163958 
     19         O     -8.717011     -5.979540      0.984510 
     20        Nb     -6.123008     -0.349942     -1.571254 
     21         O      6.020227     -3.415301     -0.676332 
     22         O      6.631688     -6.943947      0.965090 
     23         H     -2.701783      0.318961      2.709489 
     24        Nb      5.168917     -2.506464      0.780549 
     25        Nb      5.768371     -6.797008      2.766126 
     26        Nb     -4.978720     -3.481283     -0.553283 
     27         O     -6.445997     -1.077303      3.447366 
     28         O      6.761800     -2.165738      1.778186 
     29         H      0.459444     -5.551151     -0.444669 
     30         O    -10.819358     -0.608665     -0.518153 
     31         O      8.040221     -4.505001      0.940911 
     32         O     -5.944481     -4.925504      0.208879 
     33        Nb     -7.998626     -4.464496      0.338894 
     34        Nb      3.520766      0.838810      0.373578 
     35        Nb     -9.194123     -1.375277     -0.529801 
     36         H      1.396983     -0.728638      0.287609 
     37        Nb      6.638975     -5.343667     -0.206863 
     38        Nb     -1.420481     -3.966705      0.406285 
     39        Nb     -7.406113     -3.227195     -2.799565 
     40         O     -8.029171     -4.731174     -1.642672 
     41         O      1.829604     -6.114066     -0.021786 
     42        Nb      7.514772     -3.850308      2.744612 
     43         O      3.255795     -3.440497      0.252755 
     44         O     -6.847924     -2.417644     -0.537797 
     45         O      9.052903     -3.267999      3.459265 
     46         O      3.966470     -7.022831      1.800034 
     47         O      5.081339      1.970421     -0.296925 
     48         O     -4.822668     -2.484466      1.263944 
     49         O     -5.675246     -0.039777      0.608985 
     50         O      2.222112      1.332341     -0.790074 
     51         O     -3.120222     -4.123917     -0.553836 
     52         O      2.564227     -4.556758      2.492763 
     53         H      5.388374      1.687717     -1.179614 
     54         O     -9.527307     -3.220465      0.200933 
     55         O     -1.734268     -4.783154      1.942812 
     56         O     -5.462938     -3.845155     -2.378132 
     57         O     -6.479351     -1.408458     -3.144260 
     58         O     -8.399356     -0.893010      1.270827 
     59         O      2.100260     -0.825037      0.958560 
     60         O     -3.299313     -0.440916      2.567349 
     61         O      0.349953     -3.025960      0.915184 
     62         O      4.728098     -0.820177      0.045707 
     63         O     -7.423361     -3.462720      2.031736 
     64         O     -5.444132      1.173675     -2.233145 
     65         O     -9.044092     -2.201133     -2.357637 
     66         O     -7.693656     -3.831777     -4.469635 
     67         H     -1.210036     -1.427785      0.821667 
     68         O      3.330760      1.675697      1.957845 
     69         O      3.964475     -2.271145      2.502981 
     70         O     -1.964468     -1.881301      0.396554 
     71         O      5.296553     -4.525969      1.749454 
     72         H     -4.816231     -2.026268      2.107516 
end

charge -11

geometry
end

