AnalyticalFreq
end

Basis
  Core Small
  Type TZP
end

NumericalQuality Good

QTAIM 
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    Nb=2.025
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1        Nb      1.632899      1.606608      3.062462 
      2         O      2.426625      0.286641      1.755298 
      3         O      3.986877      1.853348      3.473632 
      4         O      2.136285      3.073911      1.763343 
      5         O      1.669000      3.015653      4.521549 
      6         O      1.960143      0.234429      4.512617 
      7         O     -0.168290      1.424056      2.755908 
      8         O      5.841471      0.629408      5.183193 
      9        Nb      4.452144      0.194445      1.796800 
     10        Nb      4.096167      3.574418      1.806275 
     11        Nb      3.883808      0.125919      5.141757 
     12        Nb      6.348689      2.097042      3.885936 
     13        Nb      3.525376      3.505954      5.149294 
     14         O      3.179426      4.769091      6.436948 
     15         O      4.277340     -0.936375      3.464223 
     16         O      3.795849     -1.191314      6.418360 
     17         O      8.150373      2.278656      4.192169 
     18         O      5.552757      3.413517      5.191720 
     19         O      4.803718     -1.066205      0.508474 
     20         O      4.455548      1.908350      0.717858 
     21         O      6.306756      0.688790      2.427027 
     22         O      3.702580      4.637748      3.483452 
     23         O      4.186225      4.894313      0.532351 
     24         O      6.019457      3.466466      2.434022 
     25         O      3.524548      1.793377      6.229277 
     26         H      6.078888      2.934204      1.637300 
     27         H      2.103785     -0.668744      4.220648 
end

charge -6

geometry
end

