%nprocshared=28
%mem=370MW
%chk=S_TS1.chk
#p opt=(ts, noeigentest, calcFC, maxstep=2) freq sdd/def2tzv scrf=(smd,solvent=acetonitrile)
empiricaldispersion=gd3bj pbe1pbe

TS1-(S)  DavePhos-OAc and CO2 Concerted

0 1
 Ag                -0.05374800   -0.21841300   -0.72459400
 P                  2.08201100    0.47926900    0.10486200
 C                  3.49908400   -0.72392800   -0.04020700
 C                  4.81335600   -0.22001000    0.02104900
 H                  4.98112700    0.84021900    0.17944700
 C                  5.92448000   -1.05456800   -0.15101100
 H                  6.92681600   -0.64046000   -0.09490500
 C                  5.72925300   -2.41869800   -0.41167700
 H                  6.57921500   -3.07829200   -0.56084900
 C                  4.42785000   -2.92867600   -0.47876000
 H                  4.27249700   -3.98670100   -0.67065300
 C                  3.29864600   -2.10552000   -0.28072200
 C                  1.95215800   -2.73530000   -0.40341600
 C                  0.34281600   -3.84582700   -1.88991000
 H                  0.10083600   -4.25200100   -2.86727200
 C                 -0.61035400   -3.82429100   -0.86353200
 C                 -0.28023500   -3.30732400    0.39548400
 H                 -1.02856700   -3.32508800    1.18037200
 C                  1.00546000   -2.77795400    0.66380000
 C                 -2.72032300    0.08852300    3.19450400
 C                 -3.27693000    0.19946100    2.11543400
 H                 -2.23123000   -0.01914300    4.13994300
 C                 -3.98859500    0.35680800    0.83355200
 H                 -1.61491700   -4.20007600   -1.03104200
 C                 -3.45352600    1.54134200    0.02289000
 C                 -3.93761800    1.73300000   -1.28447800
 C                 -2.49908700    2.43024000    0.53627100
 C                 -3.45795600    2.78634800   -2.07127300
 H                 -4.67540800    1.05052300   -1.69611200
 C                 -2.02491900    3.49479100   -0.24732100
 H                 -2.12206500    2.29748800    1.54470700
 C                 -2.49580000    3.67236800   -1.55561000
 H                 -3.82995900    2.91522500   -3.08376200
 H                 -1.28634000    4.17657400    0.16410800
 H                 -2.12059100    4.48871300   -2.16637100
 C                 -5.50654400    0.52364800    1.11148800
 H                 -6.01933200    0.70116100    0.16483000
 H                 -5.88482100   -0.39643700    1.56781600
 O                 -5.77351300    1.67489300    1.94213400
 H                 -5.46693600    1.50814300    2.85739100
 H                 -3.01009500   -0.83829300   -0.70349300
 O                 -1.97436000   -0.75404200   -1.49430300
 C                 -2.05453900   -0.94164900   -2.81634800
 O                 -1.08200400   -0.68703800   -3.56808500
 C                 -3.37265100   -1.46520000   -3.31889900
 H                 -3.66705100   -2.34829200   -2.74275700
 H                 -4.15041400   -0.70581200   -3.17545100
 H                 -3.30624700   -1.71170200   -4.38006200
 C                  1.61082200   -3.29810100   -1.64628900
 H                  2.34559900   -3.26419000   -2.44696300
 C                  2.06641600    1.02716900    1.92049400
 C                  3.16529600    2.02718600    2.30388700
 C                  0.67448600    1.55583600    2.30449300
 H                  2.23541500    0.08547000    2.45920700
 C                  3.09458900    2.33862600    3.80888800
 H                  3.03616000    2.95888400    1.73567100
 H                  4.15627400    1.62737500    2.05956600
 C                  0.60877500    1.86515100    3.80611600
 H                  0.45469000    2.47171100    1.73946700
 H                 -0.09154200    0.82115000    2.02961800
 C                  1.70733200    2.85752900    4.21289900
 H                  3.86734900    3.07434000    4.06863600
 H                  3.31838200    1.42225700    4.37593200
 H                 -0.38205800    2.26622800    4.05908900
 H                  0.73372400    0.93070700    4.37421200
 H                  1.67242800    3.03975000    5.29521500
 H                  1.52325800    3.82318800    3.71741700
 C                  2.64861700    1.93852100   -0.95522600
 C                  2.87412500    1.45284300   -2.39733600
 C                  1.58829500    3.05040100   -0.91433200
 H                  3.59239200    2.32313000   -0.54657300
 C                  3.24766800    2.61914700   -3.32339900
 H                  1.94739900    0.98264200   -2.76274600
 H                  3.65789000    0.68581200   -2.42483800
 C                  1.95566700    4.21102300   -1.85004100
 H                  0.61972500    2.62718700   -1.22146100
 H                  1.46603900    3.42503600    0.10861500
 C                  2.18005900    3.72104400   -3.28643200
 H                  3.37780000    2.24635800   -4.34797300
 H                  4.21490000    3.03859100   -3.00754000
 H                  1.15879400    4.96652400   -1.82305500
 H                  2.87282500    4.69698300   -1.48427300
 H                  2.47459400    4.55852000   -3.93247400
 H                  1.23446600    3.32204700   -3.68516400
 N                  1.31875500   -2.26054600    1.93711800
 C                  2.51628800   -2.73984800    2.63745500
 H                  2.87664400   -1.96811500    3.32799600
 H                  2.29372900   -3.64886400    3.22181100
 H                  3.32014100   -2.97390000    1.94069900
 C                  0.21369200   -1.99573400    2.85466600
 H                 -0.20890900   -2.91612500    3.29462800
 H                  0.58172200   -1.36921400    3.67410800
 H                 -0.58741800   -1.45497900    2.34497100
 O                 -3.85264700   -0.84959600    0.01987000
 C                 -4.28520800   -2.56134100    0.56229800
 O                 -3.95289700   -3.23361700   -0.39621300
 O                 -4.76831700   -2.48263400    1.67619800



