%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3ooh-nhcho-ts_6311+Gd

-1 1
 C                  0.13487000    0.23930700    0.06710000
 H                 -0.10833400    0.01585100    1.09099000
 H                  0.11245500   -0.54402400   -0.66919100
 H                  0.38644100    1.24815300   -0.21717600
 O                 -1.70754000    0.66655800   -0.30602700
 O                 -2.47706100   -0.55489900   -0.05962000
 H                 -2.52639500   -0.59893600    0.90703300
 N                  2.14666871   -0.23277371    0.60633734
 C                  2.20753724   -0.56610863    2.03675086
 H                  1.87273522    0.27122831    2.61266270
 H                  2.99124779   -0.11125603    0.08487820
 O                  3.14985256   -0.78778451    2.28755288

