%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3f-sch3-ts_6311+Gd_new

-1 1
 C	 0.752980000	-0.043924000	 0.002293000
 H	 0.630009000	 0.473673000	 0.936441000
 H	 0.767256000	-1.119551000	-0.006832000
 H	 0.645224000	 0.489684000	-0.924697000
 S	-1.772431000	-0.149154000	-0.019274000
 F	 2.565078000	 0.112399000	 0.018445000
 C	-1.892856000	 1.689447000	-0.003813000
 H	-1.421391000	 2.113902000	 0.889233000
 H	-1.405537000	 2.129798000	-0.880505000
 H	-2.938812000	 2.010329000	-0.010305000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


